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GF45819995

Rhodium

wire reel, 0.05m, diameter 0.25mm, hard, 99.9%

Synonym(s):

Rhodium, RH005110

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About This Item

Empirical Formula (Hill Notation):
Rh
CAS Number:
7440-16-6
Molecular Weight:
102.91
MDL number:
MFCD00011201
UNSPSC Code:
12141738
PubChem Substance ID:
329806938
NACRES:
NA.23

assay

99.9%

form

wire

manufacturer/tradename

Goodfellow 458-199-95

resistivity

4.33 μΩ-cm, 20°C

L × diam.

0.05 m × 0.25 mm

bp

3727 °C (lit.)

mp

1966 °C (lit.)

density

12.41 g/cm3 (lit.)

SMILES string

[Rh]

InChI

1S/Rh

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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General description

For updated SDS information please visit www.goodfellow.com.

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Product of Goodfellow

Storage Class

13 - Non Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

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Huw M L Davies et al.
Chemical Society reviews, 36(7), 1109-1119 (2007-06-20)
This tutorial review describes the reactions of the electron-rich heterocycles pyrrole, furan, indole and benzofuran with copper and rhodium carbenoids. Two main reaction pathways are possible, involving either a concerted non-synchronous cyclopropanation or zwitterionic intermediates. A diverse range of products
Jan Meine Ernsting et al.
Magnetic resonance in chemistry : MRC, 42(9), 721-736 (2004-08-13)
Rhodium is used for a number of large processes that rely on homogeneous rhodium-catalyzed reactions, for instance rhodium-catalyzed hydroformylation of alkenes, carbonylation of methanol to acetic acid and hydrodesulfurization of thiophene derivatives (in crude oil). Many laboratory applications in organometallic
Feng Shi et al.
Topics in current chemistry, 292, 123-164 (2010-01-01)
The catalytic activation of a C-H bond is a fundamentally important organic transformation. There are now numerous reports of palladium-mediated C-H activation by the through-space interaction of a palladium center with a neighboring C-H bond. This type of C-H activation
Huw M L Davies et al.
Chemical Society reviews, 40(4), 1857-1869 (2011-03-02)
This tutorial review presents a description of the controlling elements of intermolecular C-H functionalization by means of C-H insertion by donor/acceptor rhodium carbenes. These rhodium carbenes, readily derived from the combination of diazo compounds with dirhodium(ii) catalysts, are sufficiently reactive
Jean Bouffard et al.
Topics in current chemistry, 292, 231-280 (2010-01-01)
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms
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