B56404
4′-Bromoacetophenone
98%
Synonym(s):
1-Acetyl-4-bromobenzene
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About This Item
Linear Formula:
BrC6H4COCH3
CAS Number:
Molecular Weight:
199.04
Beilstein/REAXYS Number:
386015
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
98%
form
solid
bp
255 °C (lit.)
mp
49-51 °C (lit.)
SMILES string
CC(=O)c1ccc(Br)cc1
InChI
1S/C8H7BrO/c1-6(10)7-2-4-8(9)5-3-7/h2-5H,1H3
InChI key
WYECURVXVYPVAT-UHFFFAOYSA-N
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General description
4′-Bromoacetophenone is used as an organic building block in Heck and Suzuki coupling reactions. Generates phenyl radicals upon UV irradiation.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
>212.0 °F
flash_point_c
> 100 °C
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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Gagan Chouhan et al.
Chemical communications (Cambridge, England), (45)(45), 4809-4811 (2007-11-16)
Magnetic nanoparticle-supported proline ligand was prepared and used for the CuI catalyzed Ullmann-type coupling reactions of aryl/heteroaryl bromides with various nitrogen heterocycles to form the corresponding N-aryl products in good to excellent yields; furthermore, this magnetic nanoparticle-supported proline ligand could
R Jeon et al.
Archives of pharmacal research, 24(1), 39-43 (2001-03-10)
4'-Bromoacetophenone analogs, which are able to generate monophenyl radicals capable of hydrogen atom abstraction, were investigated as possible photoinducible DNA cleaving agents. The potential of 4'-bromoacetophenone as a possible new DNA cleaver is explored. Pyrrolecarboxatmid conjugated 4'-bromoacetophenones, in particular, DNA
Mechanochemical solid-state Suzuki reactions using an in situ generated base.
Franziska Schneider et al.
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R Tung et al.
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Lidiane S Araújo et al.
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Several microorganisms were isolated from soil/sediment samples of Antarctic Peninsula. The enrichment technique using (RS)-1-(phenyl)ethanol as a carbon source allowed us to isolate 232 psychrophile/psychrotroph microorganisms. We also evaluated the enzyme activity (oxidoreductases) for enantioselective oxidation reactions, by using derivatives
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