923443
PhMPhos
Synonym(s):
1-Diadamantylphosphino-1′-diphenylphosphinoferrocene
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About This Item
Empirical Formula (Hill Notation):
C42H48FeP2
Molecular Weight:
670.62
UNSPSC Code:
12352200
NACRES:
NA.21
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form
powder
Quality Level
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand
functional group
phosphine
Application
PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).
Learn more about MPhos ligands and catalysts
Learn more about MPhos ligands and catalysts
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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