903191
Benzyl 4-oxo-5-(triethylsilyl)-3,4-dihydropyridine-1(2H)-carboxylate
Synonym(s):
Garg silyl triflate precursor
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About This Item
Empirical Formula (Hill Notation):
C19H27NO3Si
CAS Number:
Molecular Weight:
345.51
UNSPSC Code:
12352005
form
liquid
refractive index
n/D 1.548
density
1.079 g/mL
storage temp.
−20°C
Application
Benzyl 4-oxo-5-(triethylsilyl)-3,4-dihydropyridine-1(2H)-carboxylate is a precursor to a Garg silyl triflate which upon exposure to fluoride generates a reactive azacyclic allene for cycloaddition reactions.
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Product No.
Description
Pricing
Storage Class
10 - Combustible liquids
wgk_germany
WGK 3
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Joyann S Barber et al.
Nature chemistry, 10(9), 953-960 (2018-08-01)
For over a century, the structures and reactivities of strained organic compounds have captivated the chemical community. Whereas triple-bond-containing strained intermediates have been well studied, cyclic allenes have received far less attention. Additionally, studies of cyclic allenes that bear heteroatoms
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