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765155

Sigma-Aldrich

Lithium titanate

greener alternative

spinel, electrode sheet, aluminum substrate, size 5 in. × 10 in.

Synonym(s):

LTO, Lithium titanate spinel oxide

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About This Item

Linear Formula:
Li4Ti5O12
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

grade

battery grade

description

Nominal Voltage: 1.5 V, Li/Li+

assay

≥98%

form

sheet

composition

loading, ≥80%

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

extent of labeling

≥80% loading

size

5 in. × 10 in.

thickness

25-50 μm

particle size

1.5-3 μm (typical)

capacity

150 mAh/g(minimum)
160 mAh/g(nominal at 0.1C)

mp

>1000 °C

application(s)

battery manufacturing

greener alternative category

SMILES string

[Li+].[Li+].[Li+].[Li+].[O-][Ti](=O)O[Ti](O[Ti]([O-])=O)(O[Ti]([O-])=O)O[Ti]([O-])=O

InChI

1S/4Li.12O.5Ti/q4*+1;;;;;;;;;4*-1;;;;;

InChI key

BNQVSKURWGZJMY-UHFFFAOYSA-N

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General description

Lithium titanate (LTO) is a class of electrode material that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Lithium titanate (LTO) spinel electrode sheet can be used as an anode material, which shows an ion conductivity of 10−3 Scm−1 at room temperature. It can also be used as an alternative to conventional graphite materials. It can further be used in the fabrication of high-performance lithium-ion batteries for electric vehicles (EVs).

Other Notes

Crystal Structure: Spinel, cubic, Fd-3m

Operating Condiditons:
  • Recommended maximum charge voltage: 3.0 V vs Li/Li+
  • Recommended maximum charge current: 5 C
  • Recommended cut-off voltage for discharge: 1.0 V vs Li/Li+
  • Recommended maximum discharge current: 10 C

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3


Certificates of Analysis (COA)

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Jansen, A. N.; et al.
Journal of Power Sources, 902, 81-82 (1999)
Wu, H-C.; et al.
Journal of Power Sources, 197, 301-301 (2012)
Ionic conductivity, lithium insertion and extraction of lanthanum lithium titanate
Chen CH and Amine K
Solid State Ionics, 144(1-2), 51-57 (2001)
The Li-ion rechargeable battery: a perspective
Goodenough JB and Park K
Journal of the American Chemical Society, 135(4), 1167-1176 (2013)
Electrodes with high power and high capacity for rechargeable lithium batteries
Kang K, et al.
Science, 311(5763), 977-980 (2006)

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