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710733

Sigma-Aldrich

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide

Synonym(s):

1,1-Dimethylethyl-2-methyl-1-phenylpropyl nitroxide, tert-Butyl 1-phenyl-2-methylpropyl nitroxide, NMP universal alkoxyamine nitroxide

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About This Item

Empirical Formula (Hill Notation):
C14H22NO
CAS Number:
61015-94-9
Molecular Weight:
220.33
MDL number:
MFCD16621409
UNSPSC Code:
12162002
PubChem Substance ID:
329763005

refractive index

n20/D 1.515

density

0.953 g/mL at 25 °C

storage temp.

−20°C

SMILES string

CC(C)C(N([O])C(C)(C)C)c1ccccc1

InChI

1S/C14H22NO/c1-11(2)13(15(16)14(3,4)5)12-9-7-6-8-10-12/h6-11,13H,1-5H3

InChI key

VGHCMXLEZFMZOZ-UHFFFAOYSA-N

General description

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Application

Block Copolymer Synthesis Using a Commercially Available NMP Inititator
Stable nitroxide radical useful in controlling living radical polymerizations

Certificates of Analysis (COA)

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Articles

Block Copolymer Synthesis Using a Nitroxide-mediated Radical Polymerization (NMP) Approach

A detailed article on block copolymer synthesis using a nitroxide-mediated radical polymerization (NMP) approach.

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

A Micro Review of Reversible Addition/Fragmentation Chain Transfer (RAFT) Polymerization

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

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Protocols

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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