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Key Documents

701629

Sigma-Aldrich

Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

97%

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About This Item

Empirical Formula (Hill Notation):
C16H24F6RhSb
CAS Number:
Molecular Weight:
555.02
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

assay

97%

form

powder

reaction suitability

core: rhodium
reagent type: catalyst

mp

58-60 °C

storage temp.

−20°C

SMILES string

[Rh+].F[Sb-](F)(F)(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.6FH.Rh.Sb/c2*1-2-4-6-8-7-5-3-1;;;;;;;;/h2*1-2,7-8H,3-6H2;6*1H;;/q;;;;;;;;+1;+5/p-6/b2*2-1-,8-7-;;;;;;;;

InChI key

BROZUPPJWNODCU-SXGOCSEPSA-H

Application

Catalyst for:
  • [3+2] Cycloaddition
  • Preparation of diastereomeric chiral phosphorus mon- and bidentate diamidophosphite ligands based on dianydromannitol and their use in asymmetric metallocomplex catalysis
  • C-C bond-forming hydrogenation

pictograms

Exclamation markEnvironment

signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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