686697

Chlorodi(o-tolyl)phosphine

• Synonym(s): Chlorobis(o-tolyl)phosphine, Di(o-methylphenyl)phosphine chloride, Di-o-tolylchlorophosphine, Bis(2-methylphenyl)phosphinous chloride, Chlorobis(2-methylphenyl)phosphine
• Empirical Formula (Hill Notation): C₁₄H₁₄ClP
• CAS Number: 36042-94-1
• Molecular Weight: 248.69
• MDL number: MFCD04038733
• UNSPSC Code: 12352002
• PubChem Substance ID: 329761066
• NACRES: NA.22

Properties

• form: solid
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp: 63-67 °C
• functional group: phosphine
• SMILES string: Cc1ccccc1P(Cl)c2ccccc2C
• InChI: 1S/C14H14ClP/c1-11-7-3-5-9-13(11)16(15)14-10-6-4-8-12(14)2/h3-10H,1-2H3
• InChI key: KAAGXBGJRWFWPT-UHFFFAOYSA-N

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: >230.0 °F - closed cup
• flash_point_c: > 110 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges