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673587

Sigma-Aldrich

5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphine palladium(II)

Synonym(s):

Pd(II) meso-tetra(pentafluorophenyl)porphine

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About This Item

Empirical Formula (Hill Notation):
C44H8F20N4Pd
CAS Number:
72076-09-6
Molecular Weight:
1078.95
MDL number:
MFCD01320999
UNSPSC Code:
12352103
PubChem Substance ID:
329760553
NACRES:
NA.23

form

solid

Quality Level

100

mp

>300 °C (dec.)

λmax

400 nm in acetone

storage temp.

−20°C

SMILES string

Fc1c(F)c(F)c(c(F)c1F)-c2c3ccc(n3)c(-c4c(F)c(F)c(F)c(F)c4F)c5ccc6c(-c7c(F)c(F)c(F)c(F)c7F)c8ccc(n8)c(-c9c(F)c(F)c(F)c(F)c9F)c%10ccc2n%10[Pd]n56

InChI

1S/C44H8F20N4.Pd/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;/h1-8H;/q-2;+2/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;

InChI key

GRRRJZUTYPIXFO-HQJDZOCDSA-N

Related Categories

General description

5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphine palladium(II) is a phosphorescent dye that is a derivative of palladium(II). It can be used as a singlet oxygen sensitizer due to the presence of fluorine atoms. It provides photostability and is resistant to oxidation.

Application

It can be used as a porphyrin dye with a high quantum yield for use in the fabrication of oxygen sensors.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP6900
MKCK0609
MKBX7083V
MKBS2742V
11402EE

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Composite luminescent material for dual sensing of oxygen and temperature
Borisov SM, et al.
Advances in Functional Materials, 16(12), 1536-1542 (2006)
A Robust Palladium (II)-Porphyrin Complex as Catalyst for Visible Light Induced Oxidative C? H Functionalization
To W, et al.
Chemistry?A European Journal , 19(18), 5654-5664 (2013)
Temperature-sensitive europium (III) probes and their use for simultaneous luminescent sensing of temperature and oxygen
Borisov SM and Wolfbeis OS
Analytical Chemistry, 78(14), 5094-5101 (2006)

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