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643653

Sigma-Aldrich

Aluminosilicate, mesostructured

MCM-41 (hexagonal)

Synonym(s):

MCM-41 molecular sieves

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About This Item

Linear Formula:
(SiO2)x(Al2O3)y
CAS Number:
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

form

powder

composition

aluminum, ~3%

surface area

900-1100 m2/g , BET

unit cell size

4.5-4.8 nm

pore size

0.8-1.1 cm3/g pore volume
2-4 nm pore size

application(s)

battery manufacturing

SMILES string

O=[Si]=O.O=[Al]O[Al]=O

InChI

1S/2Al.O2Si.3O/c;;1-3-2;;;

InChI key

HNPSIPDUKPIQMN-UHFFFAOYSA-N

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General description

Aluminosilicate, mesostructured (Al-MSU) is an analog of hexagonal MCM-41 that can be assembled by zeolite seeds. It is hydrothermally stable and strongly acidic, which makes it useful in catalysis and adsorption technology.

Application

Al-MSU can be used as an adsorbent in the formation of hybrid membranes for fuel cell applications. It can also be used as a catalyst for biomass pyrolysis and production of aromatic amine antioxidants.

Formula variant

(SiO2)0.9875(Al2O3)0.0125­­·xH2O

Storage Class

11 - Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


Certificates of Analysis (COA)

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Hydrothermally stable mesoporous aluminosilicates (MSU-S) assembled from zeolite seeds as catalysts for biomass pyrolysis
Triantafyllidis KS, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 99(1-2), 132-139 (2007)
Mesostructured-aluminosilicate-Nafion hybrid membranes for direct methanol fuel cells
Meenakshi S, et al.
Electrochimica Acta, 89(11), 35-44 (2013)
Aluminosilicate mesostructures with improved acidity and hydrothermal stability
Liu Y and Pinnavaia TJ
Journal of Materials Chemistry, 12(11), 3179-3190 (2002)
Mesostructured aluminosilicate alkylation catalysts for the production of aromatic amine antioxidants
Liu Y, et al.
J. Catal., 225(2), 381-387 (2004)
Steam-stable aluminosilicate mesostructures assembled from zeolite type Y seeds
Liu Y, et al.
Journal of the American Chemical Society, 122(36), 8791-8792 (2000)

Articles

Mesoporous Materials include a range of high surface area porous silicates with applications in gas adsorption, drug delivery, diagnostics and catalysis.

Mesoporous materials are formed by a self-assembly process from combined solutions of sol-gel precursors (e.g., metal alkoxides) and structure-directing amphiphiles, usually block-copolymers or surfactants.

Silica is a very popular inorganic nanomaterial used in a wide range of applications including fillers for rubber, catalyst supports, separation media, carriers in food and agriculture, and abrasive/anticaking agents in cosmetics. It is also widely believed to be an important material for biomedical applications for following reasons.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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