556955
2,8,9-Triisopropyl-2,5,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane
Synonym(s):
[2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane-2,8,9-tris(1-methylethyl)]
About This Item
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refractive index
n20/D 1.4830 (lit.)
density
0.922 g/mL at 25 °C (lit.)
SMILES string
CC(C)N1CCN2CCN(C(C)C)P1N(CC2)C(C)C
InChI
1S/C15H33N4P/c1-13(2)17-10-7-16-8-11-18(14(3)4)20(17)19(12-9-16)15(5)6/h13-15H,7-12H2,1-6H3
InChI key
DFRWCJYSXGNOFD-UHFFFAOYSA-N
Related Categories
Application
Deprotonation agent used to study the nucleophilic reactivities of benzenesulfonyl-substituted carbanions
Catalyst involved in:
- Synthesis of polymer-supported proazaphosphatranes for catalysis of amidation and transesterification reactions
- Wadsworth-Emmons reactions
- Mukaiyama aldol reactions
- Synthesis of aryl alcohols via addition reactions
Storage Class
10 - Combustible liquids
wgk_germany
WGK 3
flash_point_f
185.0 °F - closed cup
flash_point_c
85 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
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Articles
An article on Proazaphosphatranes: Verkade’s Superbases.
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