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516686

Sigma-Aldrich

Sodium thiomethoxide solution

21% in H2O

Synonym(s):

Sodium methanethiolate solution, Sodium methanethiolate, Sodium thiomethoxide solution

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About This Item

Empirical Formula (Hill Notation):
CH3NaS
Molecular Weight:
70.09
Beilstein/REAXYS Number:
3592983
UNSPSC Code:
12352100
PubChem Substance ID:
24873578
NACRES:
NA.22

concentration

21% in H2O

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Legal Information

Product of Arkema

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

80.6 °F - closed cup

flash_point_c

27 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
STBK0599
STBJ6383
STBJ4267
STBH6670
STBG4763V

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Peter C Tyler et al.
Journal of the American Chemical Society, 129(21), 6872-6879 (2007-05-10)
Transition state theory suggests that enzymatic rate acceleration (kcat/knon) is related to the stabilization of the transition state for a given reaction. Chemically stable analogues of a transition state complex are predicted to convert catalytic energy into binding energy. Because
Mild, selective deprotection of thioacetates using sodium thiomethoxide.
Wallace OB and Springer DM.
Tetrahedron Letters, 39(18), 2693-2694 (1998)
Surface-initiated reversible addition-fragmentation chain transfer (RAFT) polymerization from fine particles functionalized with trithiocarbonates.
Ohno K, et al.
Macromolecules, 44(22), 8944-8953 (2011)
Y P Pang et al.
FEBS letters, 502(3), 93-97 (2001-10-05)
Using the computer docking program EUDOC, in silico screening of a chemical database for inhibitors of human adenovirus cysteine proteinase (hAVCP) identified 2,4,5,7-tetranitro-9-fluorenone that selectively and irreversibly inhibits hAVCP in a two-step reaction: reversible binding (Ki = 3.09 microM) followed

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