498262

Diphenyl selenide

96%

• Linear Formula: (C₆H₅)₂Se
• CAS Number: 1132-39-4
• Molecular Weight: 233.17
• EC Number: 214-474-3
• MDL number: MFCD00014067
• UNSPSC Code: 12352100
• PubChem Substance ID: 24873185
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 96%
• refractive index: n20/D 1.6465 (lit.)
• bp: 115-117 °C (lit.)
• density: 1.338 g/mL at 25 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: [Se](c1ccccc1)c2ccccc2
• InChI: 1S/C12H10Se/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H
• InChI key: ORQWTLCYLDRDHK-UHFFFAOYSA-N

Description

General description

Diphenyl selenide is an organoselenium compound. Its standard enthalpies of combustion, formation and the mean bond-dissociation energy have been calculated. Its potential as a neutral carrier to develop silver-selective membrane electrode has been investigated. Diphenyl selenide undergoes oxidation to form selenoxides on treating with N-bromosuccinimide followed by alkaline hydrolysis.

Application

Used for Anti-selective Michael addition of thiols and their analogs to nitro-olefins.

Safety Information

• pictograms: GHS06,GHS08,GHS09
• signalword: Danger
• hcodes: H301 + H331,H373,H410
• pcodes: P260 - P264 - P273 - P301 + P310 - P304 + P340 + P311 - P314
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: >230.0 °F - closed cup
• flash_point_c: > 110 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter