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Sigma-Aldrich

Polybutadiene

average Mn ~3,000 by VPO

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About This Item

Linear Formula:
(CH2CH=CHCH2)n
CAS Number:
9003-17-2
MDL number:
MFCD00084398
UNSPSC Code:
12162002
PubChem Substance ID:
24867209

description

peroxide number <= 10 mval/kg

form

viscous liquid

mol wt

average Mn ~3,000 by VPO

composition

cis-1,4, 75%
trans-1,4, 24%
vinyl, 1%

refractive index

n20/D 1.524

viscosity

2,700-3,000 mPa.s(20 °C)(lit.)

mp

−6 °C

acid number

≤0.3 mg KOH/g

iodine value

420‑480 g/100g

transition temp

pour point ~−50 °C

solubility

aliphatic hydrocarbons: soluble

density

0.9 g/mL at 25 °C (lit.)

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

InChI key

IAQRGUVFOMOMEM-ONEGZZNKSA-N

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Application

Co-reactant for air curing coatings.

Features and Benefits

Low viscosity liquid that undergoes polymerization in the presence of oxygen and free radical generators. Unsaponifiable drying oil. Improves water and chemical resistance.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
07615CE
07510JS
05126AN
08510JR

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Gregory P Robbins et al.
Langmuir : the ACS journal of surfaces and colloids, 26(17), 14089-14096 (2010-08-14)
The polymersome, a fully synthetic cell mimetic, is a tunable platform for drug delivery vehicles to detect and treat disease (theranostics). Here, we design a leuko-polymersome, a polymersome with the adhesive properties of leukocytes, which can effectively bind to inflammatory
Joan M Widin et al.
Journal of the American Chemical Society, 134(8), 3834-3844 (2012-01-28)
Controlled/"living" polymerizations and tandem polymerization methodologies offer enticing opportunities to enchain a wide variety of monomers into new, functional block copolymer materials with unusual physical properties. However, the use of these synthetic methods often introduces nontrivial molecular weight polydispersities, a
P S Brown et al.
Langmuir : the ACS journal of surfaces and colloids, 28(38), 13712-13719 (2012-09-13)
Two-dimensional hexagonally ordered honeycomb surfaces have been created by solvent casting polybutadiene films under controlled humidity. Subsequent CF(4) plasmachemical fluorination introduces cross-linking and surface texturing, leading to hierarchical surfaces with roughness on both the 10 μm (honeycomb) and micrometer (texturing)
Zhi-ping Huang et al.
Journal of hazardous materials, 229-230, 251-257 (2012-06-26)
Migration appeared in the interfaces of nitrate ester plasticized polyether (NEPE) based propellant/hydroxyl-terminated polybutadiene (HTPB) based liner/ethylene propylene terpolymer (EPDM) based insulation was studied by aging at different temperatures. The migration components were extracted with solvent and determined by high
Rachel Calvet et al.
Journal of chromatography. A, 1253, 164-170 (2012-07-24)
In this study, the coupling of IGC-ID analysis and carbon blacks impregnation with increasing ratios of polymer allow us to highlight the affinity of the polymer to the solid surface. The variations of the dispersive component of the surface energy
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