Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

More Documents

403636

Sigma-Aldrich

N-(2-Pyridyl)bis(trifluoromethanesulfonimide)

96%

Synonym(s):

2-[N,N-Bis(trifluoromethylsulfonyl)amino]pyridine, N,N-Bis(trifluoromethylsulfonyl)-2-pyridylamine

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C7H4F6N2O4S2
CAS Number:
145100-50-1
Molecular Weight:
358.24
Beilstein/REAXYS Number:
5832565
MDL number:
MFCD00191834
UNSPSC Code:
12352100
PubChem Substance ID:
24865207
NACRES:
NA.22

assay

96%

form

solid

bp

80-90 °C/0.25 mmHg (lit.)

mp

40-42 °C (lit.)

storage temp.

2-8°C

SMILES string

FC(F)(F)S(=O)(=O)N(c1ccccn1)S(=O)(=O)C(F)(F)F

InChI

1S/C7H4F6N2O4S2/c8-6(9,10)20(16,17)15(5-3-1-2-4-14-5)21(18,19)7(11,12)13/h1-4H

InChI key

DXLQEJHUQKKSRB-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

N-(2-Pyridyl)bis(trifluoromethanesulfonimide) (2-[N,N-Bis(trifluoromethylsulfonyl)amino]pyridine, N,N-Bis(trifluoromethylsulfonyl)-2-pyridylamine)) is a useful triflating reagent. It has been synthesized by reacting 2-aminopyridine and triflic anhydride.

Application

N-(2-Pyridyl)bis(trifluoromethanesulfonimide) may be used in the synthesis of aryl triflates and vinyl triflates.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

N-(2-Pyridyl) bis (trifluoromethanesulfonimide).
Cossy J and Allais F.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)

Articles

Chiral Diene Ligands for Asymmetric Transformations

In the last few years, a number of chiral diene ligands have emerged for a variety of asymmetric transformations.1 This powerful new method has proven to be an efficient way for the construction of enantioenriched compounds from achiral substrates.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service