363901
2-Chloro-2-propen-1-ol
technical grade, 90%
Synonym(s):
2-Chloroallyl alcohol
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About This Item
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grade
technical grade
Quality Level
assay
90%
form
liquid
refractive index
n20/D 1.459 (lit.)
bp
133-134 °C (lit.)
density
1.162 g/mL at 25 °C (lit.)
functional group
chloro
hydroxyl
SMILES string
OCC(Cl)=C
InChI
1S/C3H5ClO/c1-3(4)2-5/h5H,1-2H2
InChI key
OSCXYTRISGREIM-UHFFFAOYSA-N
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General description
2-Chloro-2-propen-1-ol is reported to undergo photodissociation at 193nm to generate CH2CCH2OH radical intermediate. 2-Chloro-2-propen-1-ol is formed as major product during base mediated reaction of 1,2,3-trichloropropane. 2-Chloro-2-propen-1-ol is reported to react with phosphorus trichloride to yield phosphorous esters, while with phosphory chloride it yields phosphoric ester.
Application
2-Chloro-2-propen-1-ol (2-chloropropenol) may be employed as carbon supplement for the growth of Pseudomonas strains. It may be used in the preparation of 2-(4-octylphenyl)prop-2-en-1-ol.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
129.2 °F - closed cup
flash_point_c
54 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Kinetic studies of the homogeneous abiotic reactions of several chlorinated aliphatic compounds in aqueous solution.
Applied Geochemistry, 13(6), 779-785 (1998)
Applied and environmental microbiology, 59(2), 528-535 (1993-02-01)
Three Pseudomonas strains capable of utilizing 2-chloroallylalcohol (2-chloropropenol) as the sole carbon source for growth were isolated from soil. The fastest growth was observed with strain JD2, with a generation time of 3.6 h. Degradation of 2-chloroallylalcohol was accompanied by
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Derivatives of phosphorus acids and 2-chloro-2-propen-1-ol.
Russian Chemical Bulletin, 16(6), 1233-1238 (1967)
The Journal of chemical physics, 127(15), 154316-154316 (2007-10-24)
These velocity map imaging experiments characterize the photolytic generation of one of the two radical intermediates formed when OH reacts via an addition mechanism with allene. The CH2CCH2OH radical intermediate is generated photolytically from the photodissociation of 2-chloro-2-propen-1-ol at 193
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