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334162

Sigma-Aldrich

trans-1,2-Bis(phenylsulfonyl)ethylene

98%

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About This Item

Linear Formula:
C6H5SO2CH=CHSO2C6H5
CAS Number:
963-16-6
Molecular Weight:
308.37
Beilstein/REAXYS Number:
2334889
MDL number:
MFCD00066528
UNSPSC Code:
12352100
PubChem Substance ID:
24860060
NACRES:
NA.22

Quality Level

200

assay

98%

mp

221-223 °C (lit.)

SMILES string

O=S(=O)(\C=C\S(=O)(=O)c1ccccc1)c2ccccc2

InChI

1S/C14H12O4S2/c15-19(16,13-7-3-1-4-8-13)11-12-20(17,18)14-9-5-2-6-10-14/h1-12H/b12-11+

InChI key

YGBXMKGCEHIWMO-VAWYXSNFSA-N

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General description

Chiral BINAP-AuTFA- and chiral BINAP-AgTFA (TFA = trifluoroacetate anion) -promoted catalytic enantioselective 1,3-dipolar cycloadditions of iminoglycinates with trans-1,2-bis(phenylsulfonyl)ethylene were studied.

Application

trans-1,2-Bis(phenylsulfonyl)ethylene was used in total synthesis of (+)-7-deoxypancratistatin.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Binap-gold (I) trifluoroacetate as a bifunctional catalyst for the synthesis of chiral prolines through 1, 3-dipolar cycloaddition of azomethine ylides.
Martin-Rodriguez M, et al.
Tetrahedron Asymmetry, 21(9), 1184-1186 (2010)
J L Aceña et al.
Organic letters, 2(23), 3683-3686 (2000-11-14)
A new total synthesis of (+)-7-deoxypancratistatin 1 has been accomplished in 19 steps (8% overall yield) from two readly available compounds, furan and trans-1,2-bis(phenylsulfonyl)ethylene.

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