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Sigma-Aldrich

Silver acetylacetonate

98%

Synonym(s):

2,4-Pentanedione silver derivative, Ag(acac)

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About This Item

Linear Formula:
[CH3COCH=C(O-)CH3]Ag
CAS Number:
15525-64-1
Molecular Weight:
206.98
EC Number:
239-568-1
MDL number:
MFCD00000012
UNSPSC Code:
12352300
PubChem Substance ID:
24859369
NACRES:
NA.23

assay

98%

form

solid
solid

reaction suitability

core: silver

mp

100 °C (dec.) (lit.)

storage temp.

2-8°C

SMILES string

CC(=O)\C=C(\C)O[Ag]

InChI

1S/C5H8O2.Ag/c1-4(6)3-5(2)7;/h3,6H,1-2H3;/q;+1/p-1/b4-3-;

InChI key

CHACQUSVOVNARW-LNKPDPKZSA-M

Related Categories

General description

Silver acetylacenate is a metalorganic precursor with moderate solubility in polymer and organic solvents. It can be annealed to produce polymer incorporated silver nanoparticles (AgNPs).

Application

Ag(acac) can be used in the preparation of silver based catalysts and nanoparticles for potential applications in electronics, optoelectronics, and surface enhanced Raman spectroscopy.

pictograms

Exclamation markHealth hazard
GHS07,GHS08

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Preparation of silver nanoparticles via reduction of a highly CO2-soluble hydrocarbon-based metal precursor
Fan X, et al.
Industrial & Engineering Chemistry Research, 45(10), 3343-3347 (2006)
Shixia Zhan et al.
Nanomaterials (Basel, Switzerland), 9(9) (2019-09-07)
The ternary nanocomposites Fe3O4/Ag/polyoxometalates (Fe3O4/Ag/POMs) with core-shell-core nanostructure were synthesized by coating [Cu(C6H6N2O)2(H2O)]H2[Cu(C6H6N2O)2(P2Mo5O23)]·4H2O polyoxometalates on the surface of Fe3O4/Ag (core-shell) nanoparticles. The transmission electron microscopy/high resolution transmission electron microscopy (HR-TEM) and X-ray powder diffraction (XRD) analyses show that the Fe3O4/Ag/POMs

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