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301493

Sigma-Aldrich

2,4-Dimethylaniline

98%

Synonym(s):

1-Amino-2,4-dimethylbenzene, 2,4-Xylidine, 4-Amino-m-xylene

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About This Item

Linear Formula:
(CH3)2C6H3NH2
CAS Number:
95-68-1
Molecular Weight:
121.18
Beilstein/REAXYS Number:
636243
EC Number:
202-440-0
MDL number:
MFCD00007738
UNSPSC Code:
12352100
PubChem Substance ID:
24858192
NACRES:
NA.22

vapor density

4.2 (vs air)

vapor pressure

0.16 mmHg ( 25 °C)

assay

98%

form

liquid

autoignition temp.

860 °F

expl. lim.

7 %

refractive index

n20/D 1.558 (lit.)

bp

218 °C (lit.)

mp

−14.3 °C (lit.)

density

0.98 g/mL at 25 °C (lit.)

SMILES string

Cc1ccc(N)c(C)c1

InChI

1S/C8H11N/c1-6-3-4-8(9)7(2)5-6/h3-5H,9H2,1-2H3

InChI key

CZZZABOKJQXEBO-UHFFFAOYSA-N

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General description

2,4-Dimethylaniline is hydrolysis product of amitraz (sum) in pears. Electrochemical method for the determination of total amitraz residues and its final breakdown product, 2,4-dimethylaniline was reported.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

208.4 °F - closed cup

flash_point_c

98 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
STBD8576V
STBD4778V
S36971V
08120DH
S37507

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Julia Hepperle et al.
Food chemistry, 166, 240-247 (2014-07-24)
We developed a method for the hydrolysis of amitraz, and its degradation products 2,4-dimethylphenyl-N'-methylformamidine (DMPF) and 2,4-dimethylformamide (DMF) into 2,4-dimethylaniline (DMA), directly from QuEChERS extracts. The hydrolysis product DMA was analysed using liquid chromatography-electrospray tandem mass spectrometry (LC-ESI-MS/MS) in the
R Brimecombe et al.
Talanta, 71(3), 1298-1303 (2007-02-28)
Amitraz is a formamide acaracide used in the control of ticks and mites in livestock. An electrochemical method for the determination of total amitraz residues and its final breakdown product, 2,4-dimethylaniline, is presented. Cyclic voltammetry at a glassy carbon electrode
R D Brimecombe et al.
Journal of agricultural and food chemistry, 54(23), 8799-8803 (2006-11-09)
2,4-Dimethylaniline is a recalcitrant degradant of the pesticide amitraz and is also an industrial pollutant which is genotoxic, teratogenic and carcinogenic. The biological degradation of 2,4-dimethylaniline was examined and monitored by cyclic voltammetry. Pseudomonas species isolated from cattle dip tanks
S Göb et al.
Water science and technology : a journal of the International Association on Water Pollution Research, 44(5), 339-345 (2001-11-07)
Among advanced oxidation processes (AOPs), the photochemically enhanced Fenton reaction may be considered as one of the most efficient for the degradation of contaminants in industrial wastewater. This process involves a series of complex reactions. Therefore, an empirical model based
Juan F García-Reyes et al.
Analytical chemistry, 79(1), 307-321 (2006-12-30)
The identification of transformation products of pesticides in foodstuffs is a crucial task difficult to tackle, due to the lack of standards and scarce information available. In this work, we describe a methodology for the identification and structural elucidation of
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