237698

(S)-(+)-2-Butanol

99%

• Synonym(s): (S)-(+)-sec-Butyl alcohol
• Linear Formula: C₂H₅CH(OH)CH₃
• CAS Number: 4221-99-2
• Molecular Weight: 74.12
• Beilstein/REAXYS Number: 1718763
• EC Number: 224-168-1
• MDL number: MFCD00064281
• UNSPSC Code: 12352001
• PubChem Substance ID: 24854264
• NACRES: NA.22

Properties

• vapor density: 2.6 (vs air)
• Quality Level: 100
• vapor pressure: 12.5 mmHg ( 20 °C)
• assay: 99%
• form: liquid
• optical activity: [α]20/D +13°, neat
• autoignition temp.: 761 °F
• expl. lim.: 9.8 %
• refractive index: n20/D 1.397 (lit.)
• bp: 99-100 °C (lit.)
• density: 0.803 g/mL at 25 °C (lit.)
• SMILES string: CC[C@H](C)O
• InChI: 1S/C4H10O/c1-3-4(2)5/h4-5H,3H2,1-2H3/t4-/m0/s1
• InChI key: BTANRVKWQNVYAZ-BYPYZUCNSA-N

Description

Application

(S)-(+)-2-Butanol can be used:

• To synthesize chiral asymmetric perylene diimides (PDI) that spontaneously self-assemble into one-handed nanotubes that are photoconductive or fluorescent in nature.
• To synthesize bulky chiral vinyl monomers that can be radically polymerized to helical polymers with an excess screw sense.
• As chiral solvent to study excited state photo transfer of the photoacid, 5,8-dicyano-2-naphthol (DCN2) in chiral environment.

Safety Information

• pictograms: GHS02,GHS07
• signalword: Warning
• hcodes: H226 - H319 - H335 - H336
• pcodes: P210 - P233 - P240 - P241 - P242 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 1
• flash_point_f: 75.2 °F - closed cup
• flash_point_c: 24 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter