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224227

Sigma-Aldrich

Titanium(IV) oxide, rutile

powder, <5 μm, ≥99.9% trace metals basis

Synonym(s):

Titanium dioxide

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About This Item

Linear Formula:
TiO2
CAS Number:
Molecular Weight:
79.87
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

≥99.9% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: titanium

particle size

<5 μm

density

4.17 g/mL at 25 °C (lit.)

SMILES string

O=[Ti]=O

InChI

1S/2O.Ti

InChI key

GWEVSGVZZGPLCZ-UHFFFAOYSA-N

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General description

Titanium(IV) oxide is a semiconductorphotocatalyst with a band gap of 3.0 eV. It is widely used in the field of photovoltaics,sensors, and environmental remediation due to its unique properties such ashigh reactivity, stability against photocorrosion, and ease of furtherfunctionalization.

Application

Titanium(IV) oxide (TiO2) and functionalized TiO2 can be used as a photocatalyst for overall water-splitting reactions and photocatalytic hydrogen evolution.

Rutile titanium(IV) oxide exhibit a high dielectric constant and can be used as a component in low-temperature cofired ceramics (LTCC) or as a filler in organic-inorganic composites.

Au/rutileTiO2 can be used as a photocatalyst for selective aerobic oxidation of amines to corresponding imines.

Features and Benefits

Possesses improved photocatalytic activity.

Other Notes

Contains ~5% anatase

Storage Class

13 - Non Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Marine bivalves (Mytilus galloprovincialis) were exposed to titanium dioxide (10 mg L(-1)) either as engineered nanoparticles (nTiO2; fresh, or aged under simulated sunlight for 7 days) or the bulk equivalent. Inductively coupled plasma-optical emission spectrometry analyses of mussel tissues showed
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Nanotoxicology, 8(6), 654-662 (2013-07-10)
The study explored possible reproductive and endocrine effects of short-term (5 days) oral exposure to anatase TiO2 nanoparticles (0, 1, 2 mg/kg body weight per day) in rat. Nanoparticles were characterised by scanning electron microscopy (SEM) and transmission electron microscopy
D Minetto et al.
Environment international, 66, 18-27 (2014-02-11)
The innovative properties of nanomaterials make them suitable for various applications in many fields. In particular, TiO2 nanoparticles (nTiO2) are widely used in paints, in cosmetics and in sunscreens that are products accessible to the mass market. Despite the great

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