218790
Tetraphenylphosphonium chloride
98%
Synonym(s):
Chlorotetraphenylphosphorane
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About This Item
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Quality Level
assay
98%
form
solid
mp
272-274 °C (lit.)
SMILES string
[Cl-].c1ccc(cc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4
InChI
1S/C24H20P.ClH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1
InChI key
WAGFXJQAIZNSEQ-UHFFFAOYSA-M
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Application
- Tetraphenylphosphonium chloride can be used to tune the crystallinity of CH3NH3PbI3 thin film during the deposition for boosting perovskite solar cells (PSCs) device performance.
- It reacts with organometallic anionic complexes to give the corresponding salts.
- It can also be used as arylating reagents in Pd-catalyzed Heck reaction.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Tetraarylphosphonium Halides as Arylating Reagents in Pd?Catalyzed Heck and Cross?Coupling Reactions.
Angewandte Chemie (International Edition in English), 44(38), 6166-6169 (2005)
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Efficient Perovskite Solar Cells with Reduced Photocurrent Hysteresis through Tuned Crystallinity of Hybrid Perovskite Thin Films.
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