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Sigma-Aldrich

4-tert-Butyl-N,N-dimethylaniline

98%

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About This Item

Linear Formula:
(CH3)3CC6H4N(CH3)2
CAS Number:
2909-79-7
Molecular Weight:
177.29
EC Number:
220-824-6
MDL number:
MFCD00008833
UNSPSC Code:
12352100
PubChem Substance ID:
24852598
NACRES:
NA.22

Quality Level

200

assay

98%

form

liquid

refractive index

n20/D 1.529 (lit.)

bp

250-253 °C (lit.)

density

0.906 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CN(C)c1ccc(cc1)C(C)(C)C

InChI

1S/C12H19N/c1-12(2,3)10-6-8-11(9-7-10)13(4)5/h6-9H,1-5H3

InChI key

SJDILFZCXQHCRB-UHFFFAOYSA-N

Related Categories

General description

Potassium iodide catalyzed oxidative coupling of tert-butyl-N,N-dimethylaniline with indole has been investigated. It is an efficient polymerization accelerator.

Application

4-tert-Butyl-N,N-dimethylaniline was employed as amine initiator during free-radical/cationic hybrid photopolymerizations of acrylates and epoxides.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

228.2 °F - closed cup

flash_point_c

109 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCBX0147
BCBW9800
MKBJ0911V
MKBJ0156V
MKBH7268V

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Evaluation of initiator systems for controlled and sequentially curable free-radical/cationic hybrid photopolymerizations.
Oxman JD, et al.
Journal of Polymer Science: Part A, General Papers, 43(9), 1747-1756 (2005)
H Argentar et al.
Journal of the American Dental Association (1939), 102(5), 664-665 (1981-05-01)
These tests showed that DMBA, a recently commercialized amine accelerator, is more suitable from the standpoint of color for use in denture base, reline, and repair resins than is the commercially used amine, DMPT. As the curing times of all
Lan-Tao Li et al.
Organic & biomolecular chemistry, 10(48), 9519-9522 (2012-11-13)
A one-pot dual functionalization of indoles has been developed. The simultaneous C3-formylation and N-aminomethylation of indoles can be achieved using readily available potassium iodide as a catalyst and tert-butyl peroxybenzoate as a co-oxidant.

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