All Photos(2)
About This Item
Linear Formula:
ClCOOCH2CH2CH2CH3
CAS Number:
Molecular Weight:
136.58
Beilstein/REAXYS Number:
605635
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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vapor pressure
2.42 psi ( 20 °C)
Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.412 (lit.)
bp
142 °C (lit.)
density
1.074 g/mL at 25 °C (lit.)
functional group
chloro
storage temp.
2-8°C
SMILES string
CCCCOC(Cl)=O
InChI
1S/C5H9ClO2/c1-2-3-4-8-5(6)7/h2-4H2,1H3
InChI key
NRDQFWXVTPZZAZ-UHFFFAOYSA-N
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Application
- Butyl chloroformate was used in the synthesis of dextran alkyl carbonates.
- It was also used in the synthesis of S-tert-alkyl-N,N-alkoxycarbonylmethyl-dithiocarbamate, radical polymerization with reversible addition-fragmentation chain transfer agent.
- It was used as derivatization reagent in determination of linsidomine in plasma using high-performance liquid chromatographic separation with tandem mass spectrometric detection.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Flam. Liq. 3 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk_germany
WGK 1
flash_point_f
100.4 °F - closed cup
flash_point_c
38 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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F C Sutherland et al.
Journal of pharmaceutical and biomedical analysis, 22(3), 461-467 (2000-04-15)
A sensitive method for the determination of linsidomine in plasma was developed, using high-performance liquid chromatographic (HPLC) separation with tandem mass spectrometric detection. Linsidomine was derivatised with propyl chloroformate and extracted with tert-butyl methyl ether/1,2-dichloroethane (55:45, v/v), back-extracted into HCl
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Dextran alkyl carbonates were synthesized applying ethyl chloroformate, butyl chloroformate, butyl fluoroformate and 1H-imidazole-1-carboxylates. The influence of the reaction conditions on the reaction efficiency and the substitution pattern was studied in detail. The structure of the products obtained was clearly
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