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About This Item
Linear Formula:
CH3C6H4OCH3
CAS Number:
Molecular Weight:
122.16
Beilstein/REAXYS Number:
907023
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
assay
99%
form
liquid
refractive index
n20/D 1.513 (lit.)
bp
175-176 °C (lit.)
density
0.969 g/mL at 25 °C (lit.)
SMILES string
COc1cccc(C)c1
InChI
1S/C8H10O/c1-7-4-3-5-8(6-7)9-2/h3-6H,1-2H3
InChI key
OSIGJGFTADMDOB-UHFFFAOYSA-N
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Application
3-Methylanisole was used to study the functionalized core of calyciphylline A-type alkaloids.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
125.6 °F - closed cup
flash_point_c
52 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Filippo Sladojevich et al.
Organic letters, 13(19), 5132-5135 (2011-09-09)
An efficient, robust, and scalable strategy to access the functionalized core of calyciphylline A-type alkaloids has been developed starting from commercially available 3-methylanisole. Key features of this approach are an intramolecular Michael addition/allylation sequence and a ring-closing metathesis step.
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