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Key Documents

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156876

Sigma-Aldrich

N-(2-Hydroxyethyl)aniline

98%

Sinónimos:

2-(Phenylamino)ethanol, 2-Anilinoethanol, N-Phenylethanolamine

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About This Item

Fórmula lineal:
C6H5NHCH2CH2OH
Número de CAS:
122-98-5
Peso molecular:
137.18
Beilstein/REAXYS Number:
774672
MDL number:
MFCD00002832
UNSPSC Code:
12352100
PubChem Substance ID:
24849642
NACRES:
NA.22

vapor density

>1 (vs air)

vapor pressure

<0.01 mmHg ( 20 °C)

assay

98%

form

liquid

refractive index

n20/D 1.578 (lit.)

bp

278-282 °C/760 mmHg (lit.)

density

1.094 g/mL at 25 °C (lit.)

SMILES string

OCCNc1ccccc1

InChI

1S/C8H11NO/c10-7-6-9-8-4-2-1-3-5-8/h1-5,9-10H,6-7H2

InChI key

MWGATWIBSKHFMR-UHFFFAOYSA-N

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Application

N-(2-Hydroxyethyl)aniline was employed as substrate for human olfactory UDP-glucuronosyltransferase.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 - STOT SE 1

target_organs

Blood, Blood,hematopoietic system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
BCBL0248V
1433059V
1433059
1384616
1195456

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Mercedes Amat et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(28), 7724-7732 (2011-06-15)
Phenylglycinol-derived, unsaturated oxazolopiperidone lactams are extremely useful building blocks that undergo stereoselective conjugate addition reactions with organocuprates, enolates, and sulfur-stabilized anions, allowing the stereocontrolled introduction of substituents at the piperidine 4-position. The factors governing the exo- or endo-facial selectivity are
Alok K Awasthi et al.
The Journal of organic chemistry, 70(14), 5387-5397 (2005-07-02)
[reaction: see text] A practical, large-scale synthesis of a beta-amino ester 1 was developed. A chiral imine derived from (S)-phenylglycinol and 3-trimethylsilylpropanal was coupled with the Reformatsky reagent 3 with high diastereoselectivity (de > 98%) to give (SS)-4a as the
Katarina Babić et al.
Journal of chromatography. A, 1142(1), 84-92 (2006-10-19)
The performance of extractant impregnated resin (EIR) technology for chiral separation of amino-alcohols has been investigated. Phenylglycinol was selected as an archetype model enantiomer and azophenolic crown ether was used as a versatile enantioselective extractant. 1-Phenyloctane was selected as a
Mercedes Amat et al.
Chemical communications (Cambridge, England), (20)(20), 2935-2937 (2009-05-14)
The first total synthesis of (-)-16-episilicine has been completed from a phenylglycinol-derived bicyclic lactam, the key steps being stereoselective conjugate addition and alkylation reactions, and a ring-closing metathesis.
Marco Santarem et al.
The Journal of organic chemistry, 73(16), 6466-6469 (2008-07-22)
An efficient formal total synthesis of (+)-gephyrotoxin is described. The key step of our strategy relies on the diastereoselective reduction of a chiral pyrrolidine beta-enamino ester obtained by condensation of ( S)-phenylglycinol on a protected 8-hydroxy-3,6-dioxooctanoate.
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