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671584

Sigma-Aldrich

Di(1-adamantyl)-n-butylphosphine hydriodide

95%

Synonym(s):

Di(1-adamantanyl)-n-butyl-phosphonium iodide, cataCXium® AHI

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About This Item

Empirical Formula (Hill Notation):
C24H40IP
CAS Number:
714951-87-8
Molecular Weight:
486.45
MDL number:
MFCD10566973
UNSPSC Code:
12352001
PubChem Substance ID:
329760432
NACRES:
NA.22

Assay

95%

form

solid

reaction suitability

reaction type: Asymmetric synthesis
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

functional group

phosphine

SMILES string

I.CCCCP([C@]12C[C@H]3C[C@H](C[C@H](C3)C1)C2)[C@@]45C[C@@H]6C[C@@H](C[C@@H](C6)C4)C5

InChI

1S/C24H39P.HI/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;/h17-22H,2-16H2,1H3;1H/t17-,18+,19-,20-,21+,22-,23-,24-;

InChI key

IBXHWLZKSOGUFS-HDWJELNESA-N

Related Categories

General description

sold in collaboration with Solvias AG

Application

Phosphonium salts are ligand precursors for the palladium-catalyzed amination, and Suzuki coupling

Legal Information

US7148176
cataCXium is a registered trademark of Umicore AG & Co. KG

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCC7243
BCCB5813
BCCC4393
BCBS3540V
BCBR6619V

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Articles

cataCXium®

cataCXium® - Ligands and Complexes for Efficient Cross-Coupling Reactions. Cross-coupling reactions are an important class of catalytic transformations with applications in polymer science as well as in the fine chemicals and pharmaceutical industries.

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