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Merck
모든 사진(3)

주요 문서

M14102

Sigma-Aldrich

Diethylene glycol dimethyl ether

ReagentPlus®, 99%

동의어(들):

2-Methoxyethyl ether, Bis(2-methoxyethyl) ether, Dimethyldiglycol, ‘Diglyme’

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About This Item

Linear Formula:
(CH3OCH2CH2)2O
CAS Number:
Molecular Weight:
134.17
Beilstein:
1736101
EC Number:
MDL number:
UNSPSC 코드:
12352112
PubChem Substance ID:
NACRES:
NA.21
bp:
162 °C (lit.)
vapor pressure:
3 mmHg ( 20 °C)

Grade

reagent

Quality Level

vapor density

4.6 (vs air)

vapor pressure

3 mmHg ( 20 °C)

제품 라인

ReagentPlus®

분석

99%

양식

liquid

autoignition temp.

370 °F

expl. lim.

17.4 %

dilution

(for general lab use)

색상

APHA: ≤10

refractive index

n20/D 1.408 (lit.)

pH

7 (20 °C)

bp

162 °C (lit.)

mp

−64 °C (lit.)

density

0.944 g/mL at 20 °C (lit.)
0.939 g/mL at 25 °C (lit.)

SMILES string

COCCOCCOC

InChI

1S/C6H14O3/c1-7-3-5-9-6-4-8-2/h3-6H2,1-2H3

InChI key

SBZXBUIDTXKZTM-UHFFFAOYSA-N

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일반 설명

Diethylene glycol dimethyl ether (diglyme), a hydrophilic ether, is an electron-donor solvent. Its toxicity has been assessed. The effect of complexation of diglyme with lithium trifluoromethanesulfonate on the conformation has been investigated. It is reported to enhance the ability of KF-MeOH-Al2O3 (potassium fluoride-methanol-alumina) reagent to replace halogen with methoxy groups in 5,8-dihydroxy-2,3-dichloro-1,4-naphthoquinones.

애플리케이션

Diethylene glycol dimethyl ether may be used as a solvent to form a solution of sodium pentaphosphacyclopentadienide.

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

픽토그램

FlameHealth hazard

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Flam. Liq. 3 - Repr. 1B

보충제 위험성

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

134.6 °F - closed cup

Flash Point (°C)

57 °C - closed cup


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시험 성적서(COA)

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문서 라이브러리 방문

A new method for the preparation of solution of sodium pentaphosphacyclopentadienide.
Milyukov VA, et al.
Russian Chemical Bulletin, 55(7), 1297-1299 (2006)
Conformational changes in diethylene glycol dimethyl ether and poly (ethylene oxide) induced by lithium ion complexation.
Frech R and Huang W.
Macromolecules, 28(4), 1246-1251 (1995)
C J Price et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 8(1), 115-126 (1987-01-01)
Diethylene glycol dimethyl ether (diEGdiME) is structurally related to several compounds which produce reproductive and developmental toxicity, including teratogenicity in laboratory animals. In the present study, diEGdiME (0, 62.5, 125, 250, or 500 mg/kg/day) was administered by gavage in distilled
Catalytic activity of diethylene glycol dimethyl ethers in conversion of 6,7-dichloro-3-ethyl-2-ethoxynaphthazarine into echinochrome trimethyl ether.
Kochergina TY and Anufriev VF.
Russ. J. Org. Chem., 38(4), 534-537 (2002)
Simultaneous determination of six hydrophilic ethers at trace levels using coconut charcoal adsorbent and gas chromatography/mass spectrometry.
Stepien DK and Puttmann W.
Analytical and Bioanalytical Chemistry, 405(5), 1743-1751 (2013)

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