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Merck
모든 사진(7)

주요 문서

791776

Sigma-Aldrich

Potassium carbonate

anhydrous, free-flowing, Redi-Dri, ACS reagent, ≥99%

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About This Item

Linear Formula:
K2CO3
CAS Number:
Molecular Weight:
138.21
Beilstein:
4267587
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.21
분석:
≥99%
Grade:
ACS reagent
anhydrous
양식:
powder

Grade

ACS reagent
anhydrous

Quality Level

제품 라인

Redi-Dri

분석

≥99%

양식

powder

품질

free-flowing

불순물

≤0.005% silica
≤0.01% insolubles

pH

11-13 (25 °C, 138 g/L)

mp

891 °C (lit.)

음이온 미량물

chloride (Cl-): ≤0.003%
phosphate (PO43-): ≤0.001%
sulfur compounds (as SO42-): ≤0.004%

양이온 미량물

Ca: ≤0.005%
Fe: ≤5 ppm
Mg: ≤0.002%
Na: ≤0.02%
heavy metals (as Pb): ≤5 ppm

SMILES string

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

BWHMMNNQKKPAPP-UHFFFAOYSA-L

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일반 설명

Potassium carbonate is an inorganic base. It participates as a base in the palladacycle catalyzed Heck reaction of chlorobenzene with styrene. Addition of amino acids (glycine, sarcosine and proline) to K2CO3 (solvent) promotes the absorption of CO2.

애플리케이션

Potassium carbonate has been used in the preparation of disulfonated bis[4-(3-aminophenoxy)phenyl]sulfone, a disulfonated diamine monomer.

It may be used:
  • As a reagent in the synthesis of polysubstituted iodobenzene derivatives.
  • As a base for the synthesis of high molecular weight homopolymers and copolymers derived from various bisphenols.
  • As a base for the Suzuki coupling of aryl halides with aryl boronic acids.
  • In the Heck reaction of styrene and bromobenzene.

특징 및 장점

  • Increased efficiency – Eliminate time and effort of loosening hardened powders
  • Safety – Avoid risks of using tools of force to break up clumps
  • Economy – Faster preparation and solvation increase productivity and reduce costs
  • Assured quality – Excellent, expert-tested quality with no anti-caking agents
  • Flexible volumes – Available from research amounts to scale-up quantities

법적 정보

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

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픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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문서 라이브러리 방문

Adam F Nugraha et al.
Polymers, 12(7) (2020-07-24)
Several methods to synthesize poly(phenylene) block copolymers through the nickel coupling reaction were attempted to reduce the use of expensive nickel catalysts in polymerization. The model reaction for poly(phenylene) having different types of dichlorobenzene derivative monomers illustrated the potential use
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Journal of the American Chemical Society, 136(29), 10486-10492 (2014-07-09)
We have measured the single-molecule conductance of a family of oligothiophenes comprising 1-6 thiophene moieties terminated with methyl-sulfide linkers using the scanning tunneling microscope-based break-junction technique. We find an anomalous behavior: the peak of the conductance histogram distribution does not
K M Frankowski et al.
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