모든 사진(1)
About This Item
Linear Formula:
NH4SCN
CAS Number:
Molecular Weight:
76.12
Beilstein:
3595135
EC Number:
MDL number:
UNSPSC 코드:
12352300
eCl@ss:
38060604
PubChem Substance ID:
NACRES:
NA.55
추천 제품
Grade
for inorganic trace analysis
분석
99.99% trace metals basis
양식
crystals
불순물
≤0.004 meq/g I2 consumers
≤0.005% insolubles
무기 잔류물
≤0.025%
pH
4.5-6.0
mp
152-154 °C (lit.)
solubility
water: 76.1 g/L at 20 °C
음이온 미량물
chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.005%
양이온 미량물
Fe: ≤3 ppm
heavy metals: ≤5 ppm
SMILES string
N.SC#N
InChI
1S/CHNS.H3N/c2-1-3;/h3H;1H3
InChI key
SOIFLUNRINLCBN-UHFFFAOYSA-N
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일반 설명
Ammonium thiocyanate is an ammonium salt commonly used for thiocyanation reaction of organic compounds.
애플리케이션
Ammonium thiocyanate (ATC) may be used the synthesis of the following:
- Graphitic carbon nitride.
- Three-dimensional nitrogen and sulfur co-doped graphene frameworks (N/S-GFs).
- Substituted 2-aminothiazole derivatives by reacting with α-halo ketone carbonyls in the presence of N-methylimidazole.
- Thiiranes from corresponding oxiranes in the presence of LiBF4.
- 1,2,4-triazole-3-thiones by a multi-component reaction with benzohydrazide acid and acid chloride in the absence of solvent.
Applied in the formation of novel two-dimensional Cd-SCN coordination solids with unusual and tailorable, checkerboard- or herringbone-patterned structures these structures are important steps toward technologically useful materials.
특징 및 장점
Meets ACS reagent specifications.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1
보충제 위험성
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
Low-temperature synthesis of nitrogen/sulfur co-doped three-dimensional graphene frameworks as efficient metal-free electrocatalyst for oxygen reduction reaction.
Su Y, et al.
Carbon, 62, 296-301 (2013)
Efficient conversion of oxiranes to thiiranes with ammonium thiocyanate catalysed with LiBF4.
Kazemi F, et al.
J. Chem. Res. (M), 2002(4), 176-177 (2002)
Synthesis of bulk and nanoporous carbon nitride polymers from ammonium thiocyanate for photocatalytic hydrogen evolution.
Cui Y, et al
Journal of Materials Chemistry, 21(34), 13032-13039 (2011)
Thiocyanation of aromatic and heteroaromatic compounds using ammonium thiocyanate and I2O5.
Wu J, et al.
Synthetic Communications, 38(14), 2367-2373 (2008)
NBS or DEAD as effective reagents in α-thiocyanation of enolizable ketones with ammonium thiocyanate.
Reddy BVS, et al.
Tetrahedron Letters, 52(13), 1432-1435 (2011)
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