32304

Ammonium oxalate monohydrate

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 99.5-101.0%

• 동의어(들): Oxalic acid diammonium salt
• Linear Formula: (NH₄)₂C₂O₄ · H₂O
• CAS Number: 6009-70-7
• Molecular Weight: 142.11
• Beilstein: 3759830
• EC Number: 238-135-4
• MDL number: MFCD00149694
• UNSPSC 코드: 12352302
• PubChem Substance ID: 329754130
• NACRES: NA.21

속성

• Grade: ACS reagent
• Agency: USP/NF; reag. ISO; reag. Ph. Eur.
• vapor pressure: <0.1 hPa ( 20 °C)
• grade: puriss. p.a.
• 분석: 99.5-101.0%
• 양식: crystalline
• 불순물: ≤0.005% in water insoluble matters
• 무기 잔류물: ≤0.02% (as SO₄)
• pH: 6-7 (20 °C, 2.5%)
• mp: 133 °C (dec.) (lit.)
• 음이온 미량물: chloride (Cl^-): ≤5 mg/kg; nitrate (NO₃^-): ≤5 mg/kg; sulfate (SO₄^2-): ≤20 mg/kg
• 양이온 미량물: Ca: ≤10 mg/kg; Cd: ≤5 mg/kg; Cu: ≤5 mg/kg; Fe: ≤2 mg/kg; K: ≤10 mg/kg; Mg: ≤10 mg/kg; Na: ≤10 mg/kg; Pb: ≤5 mg/kg; Zn: ≤5 mg/kg
• SMILES string: OC(C(O)=O)=O.N.O.N
• InChI: 1S/C2H2O4.2H3N.H2O/c3-1(4)2(5)6;;;/h(H,3,4)(H,5,6);2*1H3;1H2
• InChI key: MSMNVXKYCPHLLN-UHFFFAOYSA-N

설명

일반 설명

Ammonium oxalate monohydrate is the diammonium salt of oxalic acid. Its refined crystal structure has been investigated by three-dimensional diffraction studies. Influence of bivalent [Mn(II), Co(II), Ni(II)] and trivalent cations [Fe(III), Cr(III)] impurities on the growth rates of ammonium oxalate monohydrate crystals has been described. Its space group and unit cell parameters have been analyzed by neutron diffraction studies. Its IR spectra has been compared with that of isolated coal-solubilizing agent (CSA).

애플리케이션

Ammonium oxalate monohydrate may be used to prepare an electrochemiluminescence (ECL) solution containing 1mM tris(2,2-bipyridyl)ruthenium(II) (Ru(bpy)₃²⁺) and 0.2mM ammonium oxalate monohydrate in a 0.1M ammonium acetate buffer at pH 5.0.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H302,H319
• 예방조치 성명서: P264 - P280 - P301 + P312 - P305 + P351 + P338 - P337 + P313 - P501
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2
• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 1
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable