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Key Documents

311375

Sigma-Aldrich

Antimony(III) chloride

ACS reagent, ≥99.0%

동의어(들):

Antimony trichloride

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About This Item

Linear Formula:
SbCl3
CAS Number:
Molecular Weight:
228.12
EC Number:
MDL number:
UNSPSC 코드:
12352302
eCl@ss:
38080204
PubChem Substance ID:
NACRES:
NB.24

Grade

ACS reagent

Quality Level

vapor density

7.9 (vs air)

vapor pressure

1 mmHg ( 49 °C)

분석

≥99.0%

형태

powder, crystals or chunks

반응 적합성

reagent type: catalyst
core: antimony

불순물

≤0.05% insol. CHCl3

mp

73.4 °C (lit.)

음이온 미량물

sulfate (SO42-): ≤0.005%

양이온 미량물

As: ≤0.02%
Ca: ≤0.005%
Cu: ≤0.001%
Fe: ≤0.002%
K: ≤0.01%
Na: ≤0.02%
Pb: ≤0.005%

SMILES string

Cl[Sb](Cl)Cl

InChI

1S/3ClH.Sb/h3*1H;/q;;;+3/p-3

InChI key

FAPDDOBMIUGHIN-UHFFFAOYSA-K

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애플리케이션

Antimony(III) chloride (SbCl3) is a Lewis acid catalyst that is used in various organic reactions such as polymerization, Friedel-Crafts acylations, reductions with NaBH4, ring opening of epoxides, cleavage of trityl ethers, Biginelli and chlorination reactions. It is also used as a precursor to synthesize other antimony salts.

픽토그램

CorrosionEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Aquatic Chronic 2 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서 라이브러리 방문

Synthesis, structural characterization and cytotoxicity of the antimony (III) chloride complex with N, N-dicyclohexyldithiooxamide.
Ozturk II, et al.
Polyhedron, 52, 1403-1410 (2013)
Antimony (III) chloride-catalysed Biginelli reaction: a versatile method for the synthesis of dihydropyrimidinones through a different reaction mechanism
Cepanec I, et al.
Tetrahedron, 63(48), 11822-11827 (2007)
Antimony (III) chloride-catalyzed ring opening of epoxides with anilines.
Singh MC and Peddinti RK.
Tetrahedron Letters, 48(41), 7354-7357 (2007)
Nucleic acid related compounds. 79. Efficient conversions of thioethers to. alpha.-fluoro thioethers with DAST or DAST/antimony (III) chloride.
Robins MJ and Wnuk SF.
The Journal of Organic Chemistry, 58(15), 3800-3800 (1993)
T Gebel
Mutation research, 412(3), 213-218 (1998-05-26)
Arsenic and antimony are two semimetals sharing some chemical as well as toxicological properties. Both elements are clastogenic but not point mutagenic in their trivalent state of valency. Environmental exposure to arsenic was proven to be associated with increased rates

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