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일반 설명
Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine.
애플리케이션
Bismuth(III) chloride may be used as a catalyst in the following processes:
- Alcoholysis, acetolysis and hydrolysis of epoxides to form the corresponding β-alkoxy and β-acetoxy alcohols and diols.
- Preparation of thiiranes from oxiranes using ammonium thiocyanate.
- Three component coupling of carbonyl compound, amine and dialkyl phosphite to form α-amino phosphonates.
- Allylation of secondary benzyl alcohols with allyltrimethylsilane.
- [4 + 2] cycloaddition between dienes and α-carbonyl ethylenic dienophiles.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
이미 열람한 고객
Daintith J
The facts on file dictionary of chemistry, 28-28 (2014)
Bismuth (III) chloride (BiCl3)-An efficient catalyst for mild, regio-and stereoselective cleavage of epoxides with alcohols, acetic Acid and water.
Mohammadpoor-Baltork I.
Synthetic Communications, 30(13), 2365-2374 (2000)
Bismuth (III) chloride-catalyzed direct deoxygenative allylation of substituted benzylic alcohols with allyltrimethylsilane
De SK & Gibbs RA.
Tetrahedron Letters, 46(48), 8345-8350 (2005)
The carbonyl-Diels-Alder reaction catalyzed by bismuth (III) chloride.
Robert H, et al.
Tetrahedron Letters, 39(10), 1161-1164 (1998)
Bismuth (III) Chloride; A Mild and Efficient Catalyst for Synthesis of Thiiranes from Oxiranes.
Mohammadpoor-Baltork I and Aliyan H.
Synthetic Communications, 28(21), 3943-3947 (1998)
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