추천 제품
Grade
technical grade
형태
powder or granules
solid
구성
available chlorine, 65%
반응 적합성
reagent type: oxidant
농도
≥65% (chlorine titration by Na2S2O3)
mp
100 °C (lit.)
density
2.35 g/mL at 25 °C (lit.)
SMILES string
ClO[Ca]OCl
InChI
1S/Ca.2ClO/c;2*1-2/q+2;2*-1
InChI key
ZKQDCIXGCQPQNV-UHFFFAOYSA-N
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일반 설명
Calcium hypochlorite has oxidizing properties. It participates as an oxidant in the preparation of diamine-benzoquinone polymers.
Calcium hypochlorite is generally used for water disinfection and as a bleaching agent.
애플리케이션
Calcium hypochlorite may be used as an oxidant for the following conversions:
- aldehydes to the corresponding acids
- primary aliphatic alcohols to methyl esters
- aliphatic primary alcohols to the corresponding carboxylic acids
Calcium hypochlorite may be used in the following conversions:
- aldehydes to the corresponding acids
- primary aliphatic alcohols to methyl esters
- primary benzyl alcohols to methyl benzoates
- propargylic alcohols to the corresponding aldehydes and ketones
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B
보충제 위험성
Storage Class Code
5.1A - Strongly oxidizing hazardous materials
WGK
WGK 2
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
The conversion of aliphatic primary alcohols to the corresponding carboxylic acids using calcium hypochlorite.
Kabalka GW, et al
Synthetic Communications, 20(11), 1617-1623 (1990)
The oxidation of alcohols and ethers using calcium hypochlorite [Ca (OCl)2].
Nwaukwa SO and Keehn PM.
Tetrahedron Letters, 23(1), 35-38 (1982)
A simple and efficient method for mild and selective oxidation of propargylic alcohols using TEMPO and calcium hypochlorite.
Reddy SR and Chadha A.
Royal Society of Chemistry Advances, 3(35), 14929-14933 (2013)
Quinone-amine polymers: 10. Use of calcium hypochlorite in the syntheses of polyamine-quinone (PAQ) polymers.
Nithianandam VS and Erhan S.
Polymer, 32(6), 1146-1149 (1991)
Calcium hypochlorite-mediated oxidation of primary alcohols to methyl esters.
McDonald CE, et al.
Tetrahedron Letters, 34(17), 2741-2744 (1993)
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