추천 제품
vapor pressure
50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)
Quality Level
100
200
제품 라인
ReagentPlus®
분석
99.9% trace metals basis
형태
liquid
반응 적합성
reagent type: catalyst
core: titanium
bp
135-136 °C (lit.)
mp
−25 °C (lit.)
density
1.73 g/mL at 20 °C (lit.)
SMILES string
Cl[Ti](Cl)(Cl)Cl
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
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일반 설명
Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) have been used for the synthesis of nanosized titanium dioxide.
애플리케이션
Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.
Along with sodium borohydride, it forms an effective reagent for the reduction of:
- carboxylic acid and acyl chloride to alcohols
- carboxamides, oximes and lactams to amines
- sulfoxides to sulfides
Titanium(IV) chloride (TiCl4) has been used as a precursor for the synthesis of Ag-TiO2@polyethylene glycol (PEG) nanoparticles. TiCl4 may also be used as one of the constituents to synthesize TiO2/Al2O3 binary oxide materials and N-(10-oxo-vinylanthracen-9-(10H)-ylidene)cyanamide.
법적 정보
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
표적 기관
Respiratory system
보충제 위험성
Storage Class Code
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
Scalable hybrid chemical manufacture to photothermal therapy: PEG-capped phototransducers
Scientific Reports, 6 (2016)
Reduction of some functional groups with titanium (IV) chloride/sodium borohydride.
Synthesis, 1980(09), 695-697 (1980)
Journal of environmental sciences (China), 60, 14-23 (2017-10-17)
TiO
Poly [N-(10-oxo-2-vinylanthracen-9(10H)-ylidene) cyanamide] as a novel cathode material for li-organic batteries.
Journal of Polymer Science Part A: Polymer Chemistry, 53(21), 2517-2523 (2015)
Influence of the sol-gel preparation method on the photocatalytic NO oxidation performance of TiO2/Al2O3 binary oxides.
Catalysis Today, 241, 25-32 (2015)
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