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Key Documents

697079

Sigma-Aldrich

Titanium tetrachloride

packaged for use in deposition systems

동의어(들):

Titanium(IV) chloride, TTC, Titanium tetrachloride

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About This Item

Linear Formula:
TiCl4
CAS Number:
Molecular Weight:
189.68
EC Number:
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.23

vapor pressure

50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)

Quality Level

분석

≥99.995% (trace metals analysis)

형태

liquid

반응 적합성

core: titanium
reagent type: catalyst

bp

135-136 °C (lit.)

mp

−25 °C (lit.)

density

1.73 g/mL at 20 °C (lit.)

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

Atomic number of base material: 22 Titanium

애플리케이션

Titanium tetrachloride may be used in the vapor synthesis of titania powder by oxidaition. It may be used as a catalyst in cross and asymmetric aldol reactions. Other possible uses of titanium tetrachloride is in the synthesis of :
  • γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds,
  • N-Phosphinoylimines and N-sulphonylimines from aromatic aldehydes,
  • Homoallyl ethers from allylsilanes and acetals.6

픽토그램

Skull and crossbonesCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

표적 기관

Respiratory system

보충제 위험성

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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시험 성적서(COA)

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

New cross-aldol reactions. Reactions of silyl enol ethers with carbonyl compounds activated by titanium tetrachloride
Mukaiyama T, et al.
Journal of the American Chemical Society, 96(24), 7503-7509 null
The titanium tetrachloride induced synthesis of N-phosphinoylimines and N-sulphonylimines directly from aromatic aldehydes
Jennings WB and Lovely CJ
Tetrahedron, 47(29), 5561-5568 (1991)
M T Crimmins et al.
The Journal of organic chemistry, 66(3), 894-902 (2001-06-30)
Asymmetric aldol additions using chlorotitanium enolates of N-acyloxazolidinone, oxazolidinethione, and thiazolidinethione propionates proceed with high diastereoselectivity for the Evans or non-Evans syn product depending on the nature and amount of the base used. With 1 equiv of titanium tetrachloride and
Syntheses of γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds in the presence of titanium tetrachloride
Hosomi A and Sakurai H
Tetrahedron Letters, 17(16), 1295-1298 (1976)
Ravit Madar et al.
Brain, behavior, and immunity, 48, 301-312 (2015-05-30)
Neuroinflammation in the central nervous system is detrimental for learning and memory, as evident form epidemiological studies linking developmental defects and maternal exposure to harmful pathogens. Postnatal infections can also induce neuroinflammatory responses with long-term consequences. These inflammatory responses can

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