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Key Documents

185302

Sigma-Aldrich

Diisopropyl ether

ReagentPlus®, 99%, contains either BHT or hydroquinone as stabilizer

동의어(들):

Isopropyl ether

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About This Item

Linear Formula:
(CH3)2CHOCH(CH3)2
CAS Number:
Molecular Weight:
102.17
Beilstein:
1731256
EC Number:
MDL number:
UNSPSC 코드:
12191502
PubChem Substance ID:
NACRES:
NA.07

vapor density

3.5 (vs air)

Quality Level

vapor pressure

120 mmHg ( 20 °C)

제품 라인

ReagentPlus®

분석

99%

형태

liquid

autoignition temp.

827 °F

expl. lim.

1-21 %, 100 °F

refractive index

n20/D 1.367 (lit.)

bp

68-69 °C (lit.)

mp

−85 °C (lit.)

density

0.725 g/mL at 25 °C (lit.)

SMILES string

CC(C)OC(C)C

InChI

1S/C6H14O/c1-5(2)7-6(3)4/h5-6H,1-4H3

InChI key

ZAFNJMIOTHYJRJ-UHFFFAOYSA-N

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일반 설명

Diisopropyl ether is a colorless liquid. It is widely used as a solvent for the isolation of fats and oils. It can be synthesized from isopropyl alcohol. Its mixture with isooctane has been added to the gasoline fuel as an antiknocking agent. Its synthesis from propylene and water in a single-pass trickle-bed reactor in the presence of an ion-exchange resin catalyst Amberlyst 15 has been proposed. Its efficacy as a fuel additive has been reported. When released in the atmosphere, it undergoes photodecomposition by reacting with OH radicals. Kinetics and mechanism of its reaction in atmosphere have been reported.

애플리케이션

Diisopropyl ether may be employed as a solvent for the preparation of aliphatic and aromatic cyanohydrins.

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

픽토그램

FlameExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Flam. Liq. 2 - STOT SE 3

표적 기관

Central nervous system

보충제 위험성

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

-20.2 °F - closed cup

Flash Point (°C)

-29 °C - closed cup


시험 성적서(COA)

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문서 라이브러리 방문

Atmospheric chemistry of automotive fuel additives: diisopropyl ether.
Wallington TJ, et al.
Environmental Science & Technology, 27(1), 98-104 (1993)
Eagleson M.
Concise Encyclopedia Chemistry, 325-325 (1994)
Single stage synthesis of diisopropyl ether-an alternative octane enhancer for lead-free petrol.
Heese FP, et al.
Catalysis Today, 49(1), 327-335 (1999)
Novel (R)-oxynitrilase sources for the synthesis of (R)-cyanohydrins in diisopropyl ether.
Kiljunen E and Kanerva LT.
Tetrahedron Asymmetry, 8(8), 1225-1234 (1997)
A Azim et al.
Bioorganic & medicinal chemistry, 9(5), 1345-1348 (2001-05-30)
An efficient lipase catalysed synthesis of optically enriched alpha-halogenated amides with concomitant optical enrichment of the starting alpha-haloesters is described. Candida antarctica lipase (CAL) was found to be a better catalyst over porcine pancreatic lipase (PPL) and Candida cylindracea lipase

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