D27802

1,4-Diazabicyclo[2.2.2]octane

ReagentPlus^®, ≥99%

• 동의어(들): TED, Triethylenediamine
• 실험식(Hill 표기법): C₆H₁₂N₂
• CAS Number: 280-57-9
• Molecular Weight: 112.17
• Beilstein: 103618
• EC Number: 205-999-9
• MDL number: MFCD00006689
• UNSPSC 코드: 12352100
• PubChem Substance ID: 57654087
• NACRES: NA.21

속성

• vapor pressure: 2.9 mmHg ( 50 °C)
• Quality Level: 200
• 제품 라인: ReagentPlus^®
• 분석: ≥99%
• 형태: crystals
• 환경친화적 대안 제품 특성: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• refractive index: n20/D 1.4634 (lit.)
• mp: 156-159 °C (lit.)
• density: 1.02 g/mL at 25 °C (lit.)
• 환경친화적 대안 카테고리: , Aligned
• SMILES string: N12CCN(CC2)CC1
• InChI: 1S/C6H12N2/c1-2-8-5-3-7(1)4-6-8/h1-6H2
• InChI key: IMNIMPAHZVJRPE-UHFFFAOYSA-N

설명

일반 설명

1,4-Diazabicyclo[2.2.2]octane (DABCO) is a bicyclic compound used as a strong base and catalyst in organic synthesis.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

1,4-Diazabicyclo[2.2.2]octane (DABCO, triethylenediamine), a caged tertiary diamine, is a commonly used strong hindered amine base in chemical synthesis. It can also be employed as a complexing ligand and as a catalyst. Its gas-phase electronic absorption spectrum, vibrational spectra, multiphoton ionization (MPI), and two-photon fluorescence excitation (TPFE) spectra have been recorded and analyzed. Proton magnetic resonance (PMR) studies of DABCO in solid state were conducted in order to determine its line width, second moment, and spin-lattice relaxation time.

애플리케이션

1,4-Diazabicyclo[2.2.2]octane (DABCO) may be used in the synthesis of isoxazole derivatives via dehydration of primary nitro compounds in the presence of dipolarophiles. DABCO may be used in the preparation of the following:

• DABCO bis(perhydrate)
• DABCO monohydrate
• DABCO hexahydrate

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

안전성 정보

• 픽토그램: GHS02,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H228,H302,H315,H318
• 예방조치 성명서: P210 - P240 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Sol. 1 - Skin Irrit. 2
• Storage Class Code: 4.1B - Flammable solid hazardous materials
• WGK: WGK 1
• Flash Point (°F): 144.0 °F - closed cup
• Flash Point (°C): 62.2 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges