B10358

p-Benzoquinone

reagent grade, ≥98%

• 동의어(들): Quinone
• Linear Formula: C₆H₄(=O)₂
• CAS Number: 106-51-4
• Molecular Weight: 108.09
• Beilstein: 773967
• EC Number: 203-405-2
• MDL number: MFCD00001591
• UNSPSC 코드: 12352005
• PubChem Substance ID: 57653913
• NACRES: NA.21

속성

• 생물학적 소스: synthetic
• Quality Level: 200
• Grade: reagent grade
• vapor density: 3.73 (vs air)
• vapor pressure: 0.1 mmHg ( 25 °C)
• 분석: ≥98%
• 형태: powder or crystals
• autoignition temp.: 815 °F
• 환경친화적 대안 제품 특성: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 113-115 °C (lit.)
• solubility: water: soluble 14.7 g/L at 20 °C
• 환경친화적 대안 카테고리: Aligned
• 저장 온도: room temp
• SMILES string: O=C1C=CC(=O)C=C1
• InChI: 1S/C6H4O2/c7-5-1-2-6(8)4-3-5/h1-4H
• InChI key: AZQWKYJCGOJGHM-UHFFFAOYSA-N
• 유전자 정보: human ... ACHE(43) , BCHE(590) , CES1(1066)

설명

일반 설명

p-Benzoquinone (PBQ) is a cyclic conjugated diketone. Its high-resolution photoelectron spectrum has been reported. The visible and near ultraviolet spectra of PBQ have been recorded and analyzed. Its addition as coagent has been reported to enhance the crosslinking rate of polypropylene initiated by the pyrolysis of peroxides. Its impact on hemoglobin (Hb) has been investigated based on immunoblots and mass spectral analysis of a smoker′s blood.

Free radical inhibitor

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

애플리케이션

p-Benzoquinone may be used to form benzofuranone derivatives on reacting with anilides of β-aminocrotonic acids via Nenitzescu reaction.

Dienophile employed in Diels-Alder cycloadditions to form naphthoquinones, and 1,4-phenanthrenediones.

Oxidant used in first step of greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.

Formal anti-Markovnikov hydroamination of terminal olefins

안전성 정보

• 픽토그램: GHS02,GHS06,GHS08,GHS05,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H228,H301 + H331,H314,H317,H335,H341,H410
• 예방조치 성명서: P210 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Sol. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flash Point (°F): 170.6 °F - closed cup
• Flash Point (°C): 77 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges