8.02410

p-Benzoquinone

for synthesis

• 동의어(들): p-Benzoquinone, p-Quinone, 1,4-Benzoquinone, 1,4-Cyclohexadiene-3,6-dione
• 실험식(Hill 표기법): C₆H₄O₂
• CAS Number: 106-51-4
• Molecular Weight: 108.09
• MDL number: MFCD00001591
• UNSPSC 코드: 12352115
• EC 인덱스 번호: 203-405-2
• NACRES: NA.22

속성

• vapor pressure: 0.12 hPa ( 20 °C)
• Quality Level: 200
• 양식: solid
• autoignition temp.: 560 °C
• 효능: 130 mg/kg LD₅₀, oral (Rat)
• pH: 4 (20 °C, 1 g/L in H₂O)
• mp: 110-113 °C
• solubility: 10 g/L
• density: 1.32 g/cm³ at 20 °C
• 벌크 밀도: 700 kg/m³
• 저장 온도: 2-30°C
• SMILES string: O=C1C=CC(=O)C=C1
• InChI: 1S/C6H4O2/c7-5-1-2-6(8)4-3-5/h1-4H
• InChI key: AZQWKYJCGOJGHM-UHFFFAOYSA-N

설명

애플리케이션

p-Benzoquinone can be used as:

• A free-radical inhibitor.
• A catalyst to synthesize highly site-selective N1-alkylated benzotriazoles by N1-alkylation of benzotriazoles with diazo compounds.
• A hydrogen acceptor and two electron oxidant in Pd-catalyzed Wacker oxidation of aryl olefins aldehydes.
• A redox mediator in Pd-catalyzed anaerobic electrooxidative homocoupling of aryl-boron derivatives.

안전성 정보

• 픽토그램: GHS02,GHS06,GHS08,GHS05,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H228,H301 + H331,H314,H317,H335,H341,H410
• 예방조치 성명서: P210 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Sol. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flash Point (°F): 170.6 °F - closed cup
• Flash Point (°C): 77 °C - closed cup