추천 제품
vapor density
3.5 (vs air)
Quality Level
vapor pressure
10 mmHg ( 36 °C)
4 mmHg ( 20 °C)
분석
99.5%
autoignition temp.
629 °F
expl. lim.
10.3 %
refractive index
n20/D 1.390 (lit.)
bp
138-140 °C (lit.)
mp
−73 °C (lit.)
solubility
water: slightly soluble
density
1.08 g/mL (lit.)
작용기
anhydride
ester
SMILES string
CC(=O)OC(C)=O
InChI
1S/C4H6O3/c1-3(5)7-4(2)6/h1-2H3
InChI key
WFDIJRYMOXRFFG-UHFFFAOYSA-N
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일반 설명
Acetic anhydride is a carboxylic acid anhydride commonly used for the acetylation of amines and alcohols. It undergoes exothermic reaction on addition of water to form acetic acid. The photodecomposition of acetic anhydride has been studied over the temperature range from 60-160°C. The impact of treating pine wood with acetic anhydride has been investigated to evaluate the toughness of pine wood.
애플리케이션
Acetic anhydride has been used in the preparation of 6-dimethylamino-2,3-naphthalenedicarboxylic anhydride. It has also been used to generate acetate ions during high resolution chemical ionization mass spectrometry (CI-ToFMS) analysis.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
120.2 °F - closed cup
Flash Point (°C)
49 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Photolysis of Acetic Anhydride.
J. Chem. Phys., 23(12), 2295-2299 (1955)
Acetic Anhydride Hydrolysis at High Acetic Anhydride to Water Ratios.
International Journal of Chemical Kinetics, 46(3), 151-160 (2014)
Toughness of pine wood chemically modified with acetic anhydride.
European Journal of Wood and Wood Products, 70(1-3), 399-400 (2012)
Acetic anhydride as a synthetic reagent.
Journal of Heterocyclic Chemistry, 13(2), 179-194 (1976)
Nature protocols, 6(12), 1990-1997 (2011-12-03)
Environment-sensitive fluorophores have different quantum yields in different solvents. 6-Dimethylaminonaphthalimide (6-DMN), for example, has a low quantum yield in aqueous solutions, but is highly fluorescent in nonpolar solvents or when bound to hydrophobic sites in proteins or membranes. 6-DMN has
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