추천 제품
product name
Acetonitrile, ≥99.5%, ACS reagent
Grade
ACS reagent
Quality Level
vapor density
1.41 (vs air)
vapor pressure
72.8 mmHg ( 20 °C)
분석
≥99.5%
형태
liquid
autoignition temp.
973 °F
expl. lim.
16 %
기술
solid phase extraction (SPE): suitable
불순물
≤0.3% water
≤0.6 μeq/g Titr. base
≤8 μeq/g Titr. acid
증발 잔류물
≤0.005%
색상
APHA: ≤10
refractive index
n20/D 1.344 (lit.)
bp
81-82 °C (lit.)
mp
−45 °C (lit.)
solubility
water: soluble
density
0.786 g/mL at 25 °C (lit.)
형식
neat
SMILES string
CC#N
InChI
1S/C2H3N/c1-2-3/h1H3
InChI key
WEVYAHXRMPXWCK-UHFFFAOYSA-N
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일반 설명
Acetonitrile (MeCN), an aliphatic nitrile, is a colorless liquid with a characteristic odor. MeCN has low viscosity, high elution strength and is highly miscible in water. It is widely used as a solvent and intermediate in organic syntheses and is transparent to UV-visible light, making it highly applicable in spectrophotometric and fluorimetric techniques. It also plays a major role as an extractant medium in liquid-liquid extraction, solid-phase extraction or microextraction.
애플리케이션
Acetonitrile may be used as solvent in the following processes:
- Organic synthesis
- Liquid-liquid extraction, solid-phase extraction or microextraction.
- Spectrophotometric and fluorimetric techniques.
- Electrolytes in lithium-ion batteries
- Determination of pKa values of organic superbases using the isodensity polarization continuum model (IPCM).
특징 및 장점
ACS solvents meet or exceed the high standards of the American Chemical Society (ACS) ,with test specifications that are specialized to every compound. According to the American Chemical Society, ACS reagent grade implies that it is a substance of sufficient purity to be used in most chemical analyses or reactions.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point (°F)
35.6 °F - closed cup
Flash Point (°C)
2.0 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Basicity of some organic superbases in acetonitrile.
Organic Letters, 3(10), 1523-1526 (2001)
Dynamics of ultrafast intramolecular charge transfer with 4-(dimethylamino) benzonitrile in acetonitrile.
The Journal of Physical Chemistry A, 110(9), 2955-2969 (2006)
Cerium (III) chloride promoted highly regioselective ring opening of epoxides and aziridines using NaN3 in acetonitrile: a facile synthesis of 1,2-azidoalcohols and 1,2-azidoamines.
Organic Letters, 4(3), 343-345 (2002)
Palladium-Catalyzed Oxidative Arylalkylation of Activated Alkenes: Dual C-H Bond Cleavage of an Arene and Acetonitrile.
Angewandte Chemie (International Edition in English), 50(52), 12578-12581 (2011)
Infrared spectra of acetonitrile and acetonitrile-d3.
J. Chem. Phys., 49, 5317-5325 (1968)
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