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일반 설명
Diphenyl diselenide (Ph2Se2) is an organoselenium compound. Its crystalline structure, toxicokinetic properties, antioxidant and anti-inflammatory activities have been investigated. Its ability to reverse the oxidative brain damage and mitochondrial dysfunction induced by acetaminophen has been studied in mice. It reacts with thallium (Tl) to form TI (SePh). It participates in a four-component radical coupling to form substituted cyclopentanes.
애플리케이션
Diphenyl diselenide (Ph2Se2) may be used in the following studies:
- methoxyselenenylation of alkenes
- dihydroxylation of double bonds
- hydrothiolation of terminal alkynes
- unsymmetrical diorganyl selenides
- 1-(phenylselenomethyl)vinyl selenides
- allylic phenyl selenides
기타 정보
Reagent for introducing the phenylselenyl group, used for elimination and oxidation reactions, review
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
이미 열람한 고객
Eco-Friendly Olefin Dihydroxylation Catalyzed by Diphenyl Diselenide.
Advanced Synthesis & Catalysis, 350(18), 2881-2884 (2008)
Samarium (II) di-iodide induced synthesis of allylic phenyl selenides from allylic acetates and diphenyl diselenide in the presence of palladium catalyst.
Chemistry Letters (Jpn), 6, 927-930 (1990)
The reaction of diphenyl diselenide with peroxydisulphate ions in methanol a convenient procedure to effect the methoxyselenenylation of alkenes.
Tetrahedron Letters, 30(11), 1417-1420 (1989)
Highly Selective Sequential Addition and Cyclization Reactions Involving Diphenyl Diselenide, an Alkyne, and Alkenes under Visible-Light Irradiation.
Angewandte Chemie (International Edition in English), 42(30), 3490-3493 (2003)
Photo-initiated addition of diphenyl diselenide to allenes.
Tetrahedron Letters, 31(41), 5931-5934 (1990)
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