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일반 설명
Diiodomethane is a solvent used as a halogen bond donor toward metal-bound halides.
Diiodomethane (CH2I2) is an iodine containing organic compound. Its decomposition in acetonitrile initiated by 310nm light has been investigated. Femtosecond pump-probe spectroscopic and ab initio molecular dynamics simulations studies of the photodecomposition of CH2I2 suggest the formation of the isomer of diiodomethane (CH2I-I) as hot photoproduct. In the atmosphere, it undergoes photolysis in the presence of ozone to afford iodine oxide (IO) which results in the formation of aerosols. Its vacuum ultraviolet (VUV) photoabsorption spectrum has been reported.
Diiodomethane (CH2I2) is an iodine containing organic compound. Its decomposition in acetonitrile initiated by 310nm light has been investigated. Femtosecond pump-probe spectroscopic and ab initio molecular dynamics simulations studies of the photodecomposition of CH2I2 suggest the formation of the isomer of diiodomethane (CH2I-I) as hot photoproduct. In the atmosphere, it undergoes photolysis in the presence of ozone to afford iodine oxide (IO) which results in the formation of aerosols. Its vacuum ultraviolet (VUV) photoabsorption spectrum has been reported.
애플리케이션
Diiodomethane has been used as a probe liquid for evaluation of the polar and dispersive components of the surface energy of the catecholamine coated fiber surfaces. It may be used for the preparation of cyclopropyl ketones, esters and amides.
Diiodomethane may be used as a probe solvent in contact angle measurement to analyze the hydrophilicity of polymer surfaces.
법적 정보
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
230.0 °F - closed cup
Flash Point (°C)
110 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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시험 성적서(COA)
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이미 열람한 고객
Anuvab Mandal et al.
The Journal of chemical physics, 140(19), 194312-194312 (2014-05-24)
The electronic absorption spectrum of diiodomethane in the 30,000-95,000 cm(-1) region is investigated using synchrotron radiation; the spectrum in the 50,000-66,500 cm(-1) region is reported for the first time. The absorption bands in the 30,000-50,000 cm(-1) region are attributed to
Michael Odelius et al.
The Journal of chemical physics, 121(5), 2208-2214 (2004-07-21)
Photodissociation of diiodomethane (CH2I2) in acetonitrile solution has been studied with ab initio molecular dynamics simulations, which show how the iso-diiodomethane photoproduct (CH2I-I) can be formed. The first excited state, described by the "restricted open-shell Kohn-Sham" density functional method, is
Solvent-and catalysts-free immobilization of tannic acid and polyvinylpyrrolidone onto PMMA surface by DBD plasma.
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Plasma Processes and Polymers (2017)
Nowsheen Goonoo et al.
Materials science & engineering. C, Materials for biological applications, 76, 13-24 (2017-05-10)
In this paper, the biomineralization potential and cellular response of novel blend films of the anionic sulfated polysaccharides kappa-carrageenan (KCG) and fucoidan (FUC) derived from seaweeds with semi-crystalline polyhydroxybutyrate (PHB) and polyhydroxybutyrate-co-valerate (PHBV), respectively, were analyzed. The incorporation of KCG
Catecholamine polymers as surface modifiers for enhancing interfacial strength of fiber-reinforced composites.
Lee W, et al.
Composites Science and Technology, 110, 53-61 (2015)
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