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Merck
모든 사진(3)

주요 문서

132942

Sigma-Aldrich

Bromoform

contains 1-3% ethanol as stabilizer, 96%

동의어(들):

Tribromomethane

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About This Item

실험식(Hill 표기법):
CHBr3
CAS Number:
Molecular Weight:
252.73
Beilstein:
1731048
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor density

8.7 (vs air)

Quality Level

vapor pressure

5 mmHg ( 20 °C)

분석

96%

양식

liquid

포함

1-3% ethanol as stabilizer

refractive index

n20/D 1.595 (lit.)

bp

146-150 °C (lit.)

mp

5-8 °C (lit.)

solubility

water: soluble 800 part
acetone: miscible
alcohol: miscible
benzene: miscible
chloroform: miscible
diethyl ether: miscible
oil: miscible
petroleum ether: miscible

density

2.89 g/mL at 25 °C (lit.)

작용기

bromo

SMILES string

BrC(Br)Br

InChI

1S/CHBr3/c2-1(3)4/h1H

InChI key

DIKBFYAXUHHXCS-UHFFFAOYSA-N

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일반 설명

Bromoform is a major organic source for atmospheric reactive bromine BrOx (Br+BrO). It is formed as a product of chlorination of drinking water. It undergoes photodissociation to form the Br2 fragment and mechanism has been investigated by cavity ring-down absorption spectroscopy.

애플리케이션

Bromoform was used to evaluate the genotoxicity of chlorodibromomethane, bromodichloromethane and bromoform.

픽토그램

FlameSkull and crossbonesEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

106.3 °F - closed cup - (own results)

Flash Point (°C)

41.3 °C - closed cup - (own results)

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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시험 성적서(COA)

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문서 라이브러리 방문

이미 열람한 고객

Hong-Yi Huang et al.
The Journal of chemical physics, 121(11), 5253-5260 (2004-09-09)
By using cavity ring-down spectroscopy technique, we have observed the channel leading to Br(2) molecular elimination following photodissociation of bromoform at 248 nm. A tunable laser beam, which is crossed perpendicular to the photolysis laser beam in a ring-down cell
Oceanic bromoform sources for the tropical atmosphere.
Quack B, et al.
Geophysical Research Letters, 31(23), 1-4 (2004)
K J Stocker et al.
Mutagenesis, 12(3), 169-173 (1997-05-01)
Chlorination of drinking water results in the formation of chlorodibromomethane, bromodichloromethane and bromoform. These trihalomethanes have all shown evidence of genotoxicity in bacterial and mammalian cell systems in vitro and some evidence of carcinogenicity in rodents. Chlorodibromomethane and bromodichloromethane have
M Valcke et al.
Regulatory toxicology and pharmacology : RTP, 59(2), 258-269 (2010-10-26)
The objective of this study was to assess the impact of the exposure route on the human kinetic adjustment factor (HKAF), for which a default value of 3.16 is used in non-cancer risk assessment. A multi-route PBPK model was modified
Bichismita Sahu et al.
The Journal of organic chemistry, 74(6), 2601-2604 (2009-02-26)
Addition of bromoform to conjugated nitroalkenes in the presence of Mg provided beta-tribromomethyl nitroalkanes in good to excellent yields and diastereoselectivity. These novel Michael adducts, formed under radical conditions, underwent elimination of HBr in the same pot under reflux to

프로토콜

US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

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