8.22340

Phosphorus pentachloride

for synthesis

• 동의어(들): Phosphorus pentachloride, Phosphorus(V) chloride
• 실험식(Hill 표기법): Cl₅P
• CAS Number: 10026-13-8
• Molecular Weight: 208.24
• MDL number: MFCD00011439
• UNSPSC 코드: 12352307
• EC 인덱스 번호: 233-060-3
• NACRES: NA.22

속성

• vapor pressure: 0.016 hPa ( 20 °C)
• Quality Level: 200
• 분석: ≥99.0% (argenometric)
• 형태: crystalline solid
• 효능: 660 mg/kg LD₅₀, oral (Rat)
• pH: 1 (5 g/L in H₂O, acidic)
• mp: 148 °C
• density: 2.1 g/cm³ at 20 °C
• 저장 온도: 2-30°C
• InChI: 1S/Cl5P/c1-6(2,3,4)5
• InChI key: UHZYTMXLRWXGPK-UHFFFAOYSA-N

설명

애플리케이션

• Phosphorylation of Glycoluryl Derivatives: New organoelement phosphorus derivatives synthesized using glycoluril and phosphorus pentachloride under controlled conditions (Salkeeva et al., 2021).


• Alcohol Amination and Cyclization: Catalyzed alcohol amination of diethanolamine by a Ru-PNP Pincer complex using phosphorus pentachloride to produce piperazine, demonstrating high conversion rates (van der Loo et al.).


• Chemical Weapons Convention Relevance: Rapid GC-MS screening of chlorides relevant to the Chemical Weapons Convention, including phosphorus pentachloride, for monitoring prohibited chemical activities (Kuitunen et al., 2020).


• Silicon Nanocrystal Functionalization: Phosphorus pentachloride used for the functionalization of silicon nanocrystals, enhancing their utility in advanced materials applications (Islam et al., 2017).

분석 메모

Assay (argentometric): ≥ 99.0 %

안전성 정보

• 픽토그램: GHS05,GHS06,GHS08
• 신호어: Danger
• 유해 및 위험 성명서: H302 - H314 - H330 - H373
• 예방조치 성명서: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P314
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation
• 표적 기관: Respiratory Tract
• 보충제 위험성: EUH014 - EUH029
• Storage Class Code: 6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 1