추천 제품
vapor pressure
93.33 hPa ( 20 °C)
Quality Level
분석
≥99% (GC)
형태
liquid
autoignition temp.
295 °C
효능
420 mg/kg LD50, oral (Rat)
2900 mg/kg LD50, skin (Rabbit)
expl. lim.
1.1-7.1 % (v/v)
pH
11.8 (20 °C, 6 g/L in H2O)
bp
83-84 °C/1013 hPa
mp
-70 °C
전이 온도
flash point -13.45 °C (DIN 51755 Part 1)
density
0.72 g/cm3 at 20 °C
저장 온도
2-30°C
InChI
1S/C6H15N/c1-5(2)7-6(3)4/h5-7H,1-4H3
InChI key
UAOMVDZJSHZZME-UHFFFAOYSA-N
일반 설명
Diisopropylamine (DIPA) is an aliphatic secondary amine commonly used as an organic base in chemical synthesis.
애플리케이션
Diisopropylamine can be used as:
It can also be used as a starting material to prepare lithium diisopropylamide (LDA), a strong non-nucleophilic base widely used in organic synthesis for deprotonation reactions.
- A reagent to synthesize furan, dihydrofuran, or butanolide derivatives by reacting with γ-ketothioesters.
- A catalyst to prepare aryl disulfides via oxidative coupling of aryl thiols in the presence of air as an oxidant.
- A base in Pd-catalyzed cross-coupling reactions such as Heck and Sonogashira reaction.
It can also be used as a starting material to prepare lithium diisopropylamide (LDA), a strong non-nucleophilic base widely used in organic synthesis for deprotonation reactions.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point (°F)
7.8 °F - closed cup
Flash Point (°C)
-13.45 °C - closed cup
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
Controlled mono and double Heck reactions in water catalyzed by an oxime-derived palladacycle
Tetrahedron Letters, 45(9), 1833-1836 (2004)
Diisopropylamine as a single catalyst in the synthesis of aryl disulfides
Green Processing and Synthesis, 7(1), 12-15 (2018)
Journal of the American Chemical Society, 133(18), 7135-7151 (2011-04-20)
Ortholithiation of 1-chloro-3-(trifluoromethyl)benzene with lithium diisopropylamide (LDA) in tetrahydrofuran at -78 °C displays characteristics of reactions in which aggregation events are rate limiting. Metalation with lithium-chloride-free LDA involves a rate-limiting deaggregation via dimer-based transition structures. The post-rate-limiting proton transfers are
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