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Merck
모든 사진(2)

주요 문서

E22201

Sigma-Aldrich

Ethyl diazoacetate

contains ≥13 wt. % dichloromethane

동의어(들):

DAAE

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About This Item

Linear Formula:
N=N=CHCOOC2H5
CAS Number:
Molecular Weight:
114.10
Beilstein:
107654
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

양식

liquid

Quality Level

포함

≥13 wt. % dichloromethane

refractive index

n20/D 1.46 (lit.)

bp

140-141 °C/720 mmHg (lit.)

mp

−22 °C (lit.)

solubility

water: slightly soluble

density

1.085 g/mL at 25 °C (lit.)

저장 온도

2-8°C

SMILES string

CCOC(=O)C=[N+]=[N-]

InChI

1S/C4H6N2O2/c1-2-8-4(7)3-6-5/h3H,2H2,1H3

InChI key

YVPJCJLMRRTDMQ-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

Reagent for ruthenium-catalyzed asymmetric cyclopropanation of alkenes.

관련 제품

제품 번호
설명
가격

픽토그램

FlameHealth hazardExclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 3 - Self-react. E - Skin Irrit. 2

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

Flash Point (°F)

116.6 °F - closed cup

Flash Point (°C)

47 °C - closed cup


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문서 라이브러리 방문

Palladium-catalyzed cross-coupling of aryl or vinyl iodides with ethyl diazoacetate.
Cheng Peng et al.
Journal of the American Chemical Society, 129(28), 8708-8709 (2007-06-26)
Tat-Shing Lai et al.
Dalton transactions (Cambridge, England : 2003), (40)(40), 4845-4851 (2006-10-13)
With the iron(III) complex of the Halterman iron porphyrin [P*Fe(Cl)] and ethyl diazoacetate (EDA) as catalyst and carbene source, respectively, styrene-type substrates were converted to cyclopropyl esters with high trans/cis ratio (not less than 12) and high enantioselectivity for the
Detian Gao et al.
The Journal of organic chemistry, 73(20), 8057-8068 (2008-09-19)
Several representative acetylenic sulfones were immobilized on a polymer support derived from Merrifield resin by means of ester linkers that were used to couple free carboxylic acid groups on the solid support with benzylic hydroxyl functions on the arylsulfonyl moieties
Chan Pil Park et al.
The Journal of organic chemistry, 74(16), 6231-6236 (2009-07-28)
Formal aromatic C-H insertion of rhodium(II) carbenoid was intensively investigated to develop a new methodology and probe its mechanism. Contrasting with the previously proposed direct C-H insertion, the mechanism was revealed to be electrophilic aromatic substitution, which was supported by
Tetrahedron Letters, 45, 5649-5649 (2004)

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