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Merck
모든 사진(5)

Key Documents

A88255

Sigma-Aldrich

p-Anisidine

99%

동의어(들):

4-Aminoanisole, 4-Methoxyaniline

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About This Item

Linear Formula:
CH3OC6H4NH2
CAS Number:
Molecular Weight:
123.15
Beilstein:
471556
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

99%

형태

solid

autoignition temp.

959 °F

bp

240-243 °C (lit.)

mp

56-59 °C (lit.)

SMILES string

COc1ccc(N)cc1

InChI

1S/C7H9NO/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3

InChI key

BHAAPTBBJKJZER-UHFFFAOYSA-N

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애플리케이션

p-Anisidine can undergo aerobic oxidation in the presence of gold catalysts to form aromatic azo compounds.
p-Anisidine can be used:
  • In the diastereoselective and enantioselective synthesis of CF3-substituted azoridines catalyzed by a chiral Bronsted acid.
  • To prepare 4-organoselenium-quinolines through multi-component Povarov reaction with ethyl glyoxylate and ethynyl(phenyl)selane, catalyzed by Yb(OTf)3.
  • As a starting material to synthesize 3-fluoro-6-methoxyquinoline in two steps.,
  • To prepare N-PMP protected α-aminopropargylphosphonates by reacting with terminal alkynes and diethyl formylphosphonate hydrate using silver(I) triflate as a catalyst.

픽토그램

Skull and crossbonesHealth hazardEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Carc. 1B - STOT RE 2

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point (°F)

251.6 °F - closed cup

Flash Point (°C)

122 °C - closed cup


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Dima A Sabbah et al.
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Ytterbium (III)-catalyzed three-component reactions: synthesis of 4-organoselenium-quinolines
de Oliveira IM
New. J. Chem., 41(18), 9884-9888 (2017)
A Facile Two-Step Synthesis of 3-Fluoro-6-methoxyquinoline
Li B, et al.
Organic Process Research & Development, 12(6), 1273-1275 (2008)
Silver (I) triflate-catalyzed direct synthesis of N-PMP protected α-aminopropargylphosphonates from terminal alkynes
Dodda R and Zhao C
Organic Letters, 9(1), 165-167 (2007)

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