추천 제품
product name
4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate, ≥97.0%
Quality Level
분석
≥97.0%
형태
crystals
mp
35-40 °C
응용 분야
peptide synthesis
작용기
carbonate
nitro
저장 온도
2-8°C
SMILES string
C[Si](C)(C)CCOC(=O)Oc1ccc(cc1)[N+]([O-])=O
InChI
1S/C12H17NO5Si/c1-19(2,3)9-8-17-12(14)18-11-6-4-10(5-7-11)13(15)16/h4-7H,8-9H2,1-3H3
InChI key
ZAQWGGKIMQIVGM-UHFFFAOYSA-N
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애플리케이션
4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate can be used as:
- A protecting group for an amine in one of the key synthetic steps of kottamide E total synthesis.
- A starting material to prepare a cis-butene derivative, which is used as a polymer terminating agent in the synthesis of monotelechelic glycopolymers.
기타 정보
Reagent for the introduction of the TEOC-amino protecting group which can be cleaved by F-
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
이미 열람한 고객
The Journal of Organic Chemistry, 54, 5551-5551 (1989)
Journal of the Chemical Society. Chemical Communications, 358-358 (1978)
Hoppe-Seyler's Zeitschrift fur physiologische Chemie, 362(9), 1289-1292 (1981-09-01)
2-(Trimethylsilyl)ethyl-4-nitrophenyl carbonate has been prepared as a new reagent for the introduction of the 2-(trimethylsilyl)ethyloxycarbonyl group into amino acids or amino acid derivatives. The resulting N alpha-protected amino acids were found to represent suitable intermediates for the synthesis of peptides.
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
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